Copper(II) organic compounds as intermediates of photochemical transformations of quaternary ammonium tetrachlorocuprates
Publication type: Journal Article
Publication date: 2008-08-20
scimago Q3
wos Q4
SJR: 0.205
CiteScore: 1.3
Impact factor: 1.0
ISSN: 00125008, 16083113
General Chemistry
Abstract
171 Stable organometallic compounds with a Cu(II)–C σ bond have not been described [1]. Pulse radiolysis and photolysis of divalent copper salts in aqueous solutions [2, 3] and in n -donor solvents [4] gave short-lived copper complexes with organic radicals in which the copper oxidation state was presumably two. Dissociation [2] CuR + Cu + + R • and bimolecular processes [3] 2CuR + 2Cu + + R 2 , CuR + + H 3 O + Cu 2+ + RH + H 2 O, were considered as the key routes for the destruction of these complexes. Copper(II) Organic Compounds as Intermediates of Photochemical Transformations of Quaternary Ammonium Tetrachlorocuprates E. N. Golubeva a, A. V. Lobanov a , V. I. Pergushov a , N. A. Chumakova a, and A. I. Kokorin b Presented by Academician A.L. Buchachenko February 5, 2008
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Golubeva E. N. et al. Copper(II) organic compounds as intermediates of photochemical transformations of quaternary ammonium tetrachlorocuprates // Doklady Chemistry. 2008. Vol. 421. No. 2. pp. 171-174.
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Golubeva E. N., Lobanov A. V., Pergushov V., Chumakova N. A., Kokorin A. I. Copper(II) organic compounds as intermediates of photochemical transformations of quaternary ammonium tetrachlorocuprates // Doklady Chemistry. 2008. Vol. 421. No. 2. pp. 171-174.
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TY - JOUR
DO - 10.1134/S0012500808080016
UR - https://doi.org/10.1134/S0012500808080016
TI - Copper(II) organic compounds as intermediates of photochemical transformations of quaternary ammonium tetrachlorocuprates
T2 - Doklady Chemistry
AU - Golubeva, E. N.
AU - Lobanov, A. V.
AU - Pergushov, V.I.
AU - Chumakova, N A
AU - Kokorin, A I
PY - 2008
DA - 2008/08/20
PB - Pleiades Publishing
SP - 171-174
IS - 2
VL - 421
SN - 0012-5008
SN - 1608-3113
ER -
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@article{2008_Golubeva,
author = {E. N. Golubeva and A. V. Lobanov and V.I. Pergushov and N A Chumakova and A I Kokorin},
title = {Copper(II) organic compounds as intermediates of photochemical transformations of quaternary ammonium tetrachlorocuprates},
journal = {Doklady Chemistry},
year = {2008},
volume = {421},
publisher = {Pleiades Publishing},
month = {aug},
url = {https://doi.org/10.1134/S0012500808080016},
number = {2},
pages = {171--174},
doi = {10.1134/S0012500808080016}
}
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MLA
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Golubeva, E. N., et al. “Copper(II) organic compounds as intermediates of photochemical transformations of quaternary ammonium tetrachlorocuprates.” Doklady Chemistry, vol. 421, no. 2, Aug. 2008, pp. 171-174. https://doi.org/10.1134/S0012500808080016.