volume 42 issue 4 pages 297-304

Nonlinear optical properties of systems based on ruthenium(II) tetra-15-crown-5-phthalocyaninate

Publication typeJournal Article
Publication date2008-07-30
scimago Q4
wos Q4
SJR0.178
CiteScore0.9
Impact factor0.6
ISSN00181439, 16083148
Physical and Theoretical Chemistry
Abstract
The third-order nonlinear optical properties of the ruthenium (II) complex with tetra-15-crown-5-phthalocyanine and axially coordinated triethylenediamine molecules (R4Pc)Ru(TED)2 were analyzed by means of the z-scanning technique. A solution of (R4Pc)Ru(TED)2 in tetrachloroethane was exposed to nanosecond laser pulses at a wavelength of 1064 nm. It was found that the third-order molecular polarizability of the Ru(II) complex is 4.5 × 10−32 cm4/C (esu). The polarizability per molecule increases by a factor of 3.6 when the single molecule occurs in a supramolecular assembly of (R4Pc)Ru(TED)2 complexes. The photoelectric and photorefractive properties at 1064 nm of polymer composites, determined by the supramolecular assemblies that exhibits optical absorption and photoelectric sensitivity in the near IR region, are reported.
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GRISHINA A. D. et al. Nonlinear optical properties of systems based on ruthenium(II) tetra-15-crown-5-phthalocyaninate // High Energy Chemistry. 2008. Vol. 42. No. 4. pp. 297-304.
GOST all authors (up to 50) Copy
GRISHINA A. D., Gorbunova Y. G., Enakieva Yu. Yu., KRIVENKO T. V., Savel'ev V., Vannikov A. V., Tsivadze A. Y. Nonlinear optical properties of systems based on ruthenium(II) tetra-15-crown-5-phthalocyaninate // High Energy Chemistry. 2008. Vol. 42. No. 4. pp. 297-304.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S0018143908040115
UR - http://link.springer.com/10.1134/S0018143908040115
TI - Nonlinear optical properties of systems based on ruthenium(II) tetra-15-crown-5-phthalocyaninate
T2 - High Energy Chemistry
AU - GRISHINA, A. D.
AU - Gorbunova, Yu. G.
AU - Enakieva, Yu Yu
AU - KRIVENKO, T. V.
AU - Savel'ev, V.V.
AU - Vannikov, A. V.
AU - Tsivadze, A. Yu.
PY - 2008
DA - 2008/07/30
PB - Pleiades Publishing
SP - 297-304
IS - 4
VL - 42
SN - 0018-1439
SN - 1608-3148
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2008_GRISHINA,
author = {A. D. GRISHINA and Yu. G. Gorbunova and Yu Yu Enakieva and T. V. KRIVENKO and V.V. Savel'ev and A. V. Vannikov and A. Yu. Tsivadze},
title = {Nonlinear optical properties of systems based on ruthenium(II) tetra-15-crown-5-phthalocyaninate},
journal = {High Energy Chemistry},
year = {2008},
volume = {42},
publisher = {Pleiades Publishing},
month = {jul},
url = {http://link.springer.com/10.1134/S0018143908040115},
number = {4},
pages = {297--304},
doi = {10.1134/S0018143908040115}
}
MLA
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MLA Copy
GRISHINA, A. D., et al. “Nonlinear optical properties of systems based on ruthenium(II) tetra-15-crown-5-phthalocyaninate.” High Energy Chemistry, vol. 42, no. 4, Jul. 2008, pp. 297-304. http://link.springer.com/10.1134/S0018143908040115.