Photochemistry of tetraalkylammonium tetrachlorocuprates in low-temperature matrices
Publication type: Journal Article
Publication date: 2009-09-09
scimago Q4
wos Q4
SJR: 0.178
CiteScore: 0.9
Impact factor: 0.6
ISSN: 00181439, 16083148
Physical and Theoretical Chemistry
Abstract
The product composition and the principles of photochemical transformations of tetrahexylammonium tetrachlorocuprate [(RH)4N+]2[CuIICl4]2− (RH = C6H13) in 2-chlorobutane at 77 K have been found out by ESR spectroscopy. It has been shown that the photolysis of [(RH)4N+]2 [CuIICl4]2− results in the formation of alkyl radicals (R⊙), presumably, anions [CuICl3]2− and organic copper(II) compounds {CuIIR}. A reduction in the quantum yield of primary photolysis products during the reaction, nonequivalence of the quantum yield of the buildup of paramagnetic photolysis products to that of [CuIICl4]2− consumption, and a decrease in the total number of paramagnetic particles in the system during the photolysis have been revealed. A photolysis mechanism involving both photochemical and thermal processes is proposed.
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12
Total citations:
12
Citations from 2024:
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(33.33%)
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Lobanov A. V. et al. Photochemistry of tetraalkylammonium tetrachlorocuprates in low-temperature matrices // High Energy Chemistry. 2009. Vol. 43. No. 5. pp. 384-390.
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Lobanov A. V., Golubeva E. N., Zubanova E. M., Melnikov M. Ya. Photochemistry of tetraalkylammonium tetrachlorocuprates in low-temperature matrices // High Energy Chemistry. 2009. Vol. 43. No. 5. pp. 384-390.
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RIS
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TY - JOUR
DO - 10.1134/S0018143909050099
UR - https://doi.org/10.1134/S0018143909050099
TI - Photochemistry of tetraalkylammonium tetrachlorocuprates in low-temperature matrices
T2 - High Energy Chemistry
AU - Lobanov, A. V.
AU - Golubeva, E. N.
AU - Zubanova, E M
AU - Melnikov, M Ya
PY - 2009
DA - 2009/09/09
PB - Pleiades Publishing
SP - 384-390
IS - 5
VL - 43
SN - 0018-1439
SN - 1608-3148
ER -
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BibTex (up to 50 authors)
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@article{2009_Lobanov,
author = {A. V. Lobanov and E. N. Golubeva and E M Zubanova and M Ya Melnikov},
title = {Photochemistry of tetraalkylammonium tetrachlorocuprates in low-temperature matrices},
journal = {High Energy Chemistry},
year = {2009},
volume = {43},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134/S0018143909050099},
number = {5},
pages = {384--390},
doi = {10.1134/S0018143909050099}
}
Cite this
MLA
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Lobanov, A. V., et al. “Photochemistry of tetraalkylammonium tetrachlorocuprates in low-temperature matrices.” High Energy Chemistry, vol. 43, no. 5, Sep. 2009, pp. 384-390. https://doi.org/10.1134/S0018143909050099.
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