Proton conductivity of M x H3-x PX12O40 and M x H4-x SiX12O40 (M = Rb, Cs; X = W, Mo) acid salts of heteropolyacids
Тип публикации: Journal Article
Дата публикации: 2015-10-11
scimago Q4
wos Q4
white level БС2
SJR: 0.183
CiteScore: 1.3
Impact factor: 0.7
ISSN: 00201685, 16083172
Materials Chemistry
Metals and Alloys
Inorganic Chemistry
General Chemical Engineering
Краткое описание
We have studied the electrical conductivity of rubidium and cesium acid salts of tungstophosphoric, tungstosilicic, molybdophosphoric, and molybdosilicic heteropolyacids. The materials have the form of hollow spheres up to 2 μm in size, and their surface layer is formed by nanoparticles. The ionic conductivity of the salts has been measured at different relative humidities (from 30 to 95%) in a wide temperature range (from–40 to 90°C). The highest conductivity is offered by the RbxH4–xSiW12O40 samples (σ = 5.3 × 10–4 S/cm at 30°C and 30% RH). Near 0°C, the materials undergo a phase transition which involves water crystallization and a change in activation energy, but their high proton conductivity persists even at negative temperatures.
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Safronova E. Y. et al. Proton conductivity of M x H3-x PX12O40 and M x H4-x SiX12O40 (M = Rb, Cs; X = W, Mo) acid salts of heteropolyacids // Inorganic Materials. 2015. Vol. 51. No. 11. pp. 1157-1162.
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Safronova E. Y., Osipov A. K., Baranchikov A. E., Yaroslavtsev A. B. Proton conductivity of M x H3-x PX12O40 and M x H4-x SiX12O40 (M = Rb, Cs; X = W, Mo) acid salts of heteropolyacids // Inorganic Materials. 2015. Vol. 51. No. 11. pp. 1157-1162.
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TY - JOUR
DO - 10.1134/S0020168515110102
UR - http://link.springer.com/10.1134/S0020168515110102
TI - Proton conductivity of M x H3-x PX12O40 and M x H4-x SiX12O40 (M = Rb, Cs; X = W, Mo) acid salts of heteropolyacids
T2 - Inorganic Materials
AU - Safronova, E. Yu.
AU - Osipov, A K
AU - Baranchikov, A E
AU - Yaroslavtsev, A. B.
PY - 2015
DA - 2015/10/11
PB - Pleiades Publishing
SP - 1157-1162
IS - 11
VL - 51
SN - 0020-1685
SN - 1608-3172
ER -
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@article{2015_Safronova,
author = {E. Yu. Safronova and A K Osipov and A E Baranchikov and A. B. Yaroslavtsev},
title = {Proton conductivity of M x H3-x PX12O40 and M x H4-x SiX12O40 (M = Rb, Cs; X = W, Mo) acid salts of heteropolyacids},
journal = {Inorganic Materials},
year = {2015},
volume = {51},
publisher = {Pleiades Publishing},
month = {oct},
url = {http://link.springer.com/10.1134/S0020168515110102},
number = {11},
pages = {1157--1162},
doi = {10.1134/S0020168515110102}
}
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MLA
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Safronova, E. Yu., et al. “Proton conductivity of M x H3-x PX12O40 and M x H4-x SiX12O40 (M = Rb, Cs; X = W, Mo) acid salts of heteropolyacids.” Inorganic Materials, vol. 51, no. 11, Oct. 2015, pp. 1157-1162. http://link.springer.com/10.1134/S0020168515110102.
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