Proton conductivity of M x H3-x PX12O40 and M x H4-x SiX12O40 (M = Rb, Cs; X = W, Mo) acid salts of heteropolyacids
Publication type: Journal Article
Publication date: 2015-10-11
scimago Q4
wos Q4
SJR: 0.183
CiteScore: 1.3
Impact factor: 0.7
ISSN: 00201685, 16083172
Materials Chemistry
Metals and Alloys
Inorganic Chemistry
General Chemical Engineering
Abstract
We have studied the electrical conductivity of rubidium and cesium acid salts of tungstophosphoric, tungstosilicic, molybdophosphoric, and molybdosilicic heteropolyacids. The materials have the form of hollow spheres up to 2 μm in size, and their surface layer is formed by nanoparticles. The ionic conductivity of the salts has been measured at different relative humidities (from 30 to 95%) in a wide temperature range (from–40 to 90°C). The highest conductivity is offered by the RbxH4–xSiW12O40 samples (σ = 5.3 × 10–4 S/cm at 30°C and 30% RH). Near 0°C, the materials undergo a phase transition which involves water crystallization and a change in activation energy, but their high proton conductivity persists even at negative temperatures.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
|
|
|
Petroleum Chemistry
2 publications, 10.53%
|
|
|
Russian Journal of Inorganic Chemistry
2 publications, 10.53%
|
|
|
Solid State Sciences
2 publications, 10.53%
|
|
|
Membranes and Membrane Technologies
1 publication, 5.26%
|
|
|
Mendeleev Communications
1 publication, 5.26%
|
|
|
Journal of Analytical Chemistry
1 publication, 5.26%
|
|
|
E3S Web of Conferences
1 publication, 5.26%
|
|
|
Journal of Porous Materials
1 publication, 5.26%
|
|
|
Solid State Ionics
1 publication, 5.26%
|
|
|
Polymer
1 publication, 5.26%
|
|
|
Materials Today: Proceedings
1 publication, 5.26%
|
|
|
Materials Science and Engineering B: Solid-State Materials for Advanced Technology
1 publication, 5.26%
|
|
|
Journal of Solid State Chemistry
1 publication, 5.26%
|
|
|
RSC Advances
1 publication, 5.26%
|
|
|
Journal of Composites Science
1 publication, 5.26%
|
|
|
1
2
|
Publishers
|
1
2
3
4
5
6
7
8
|
|
|
Elsevier
8 publications, 42.11%
|
|
|
Pleiades Publishing
6 publications, 31.58%
|
|
|
EDP Sciences
1 publication, 5.26%
|
|
|
Springer Nature
1 publication, 5.26%
|
|
|
Royal Society of Chemistry (RSC)
1 publication, 5.26%
|
|
|
MDPI
1 publication, 5.26%
|
|
|
1
2
3
4
5
6
7
8
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
19
Total citations:
19
Citations from 2024:
1
(5%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Safronova E. Y. et al. Proton conductivity of M x H3-x PX12O40 and M x H4-x SiX12O40 (M = Rb, Cs; X = W, Mo) acid salts of heteropolyacids // Inorganic Materials. 2015. Vol. 51. No. 11. pp. 1157-1162.
GOST all authors (up to 50)
Copy
Safronova E. Y., Osipov A. K., Baranchikov A. E., Yaroslavtsev A. B. Proton conductivity of M x H3-x PX12O40 and M x H4-x SiX12O40 (M = Rb, Cs; X = W, Mo) acid salts of heteropolyacids // Inorganic Materials. 2015. Vol. 51. No. 11. pp. 1157-1162.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S0020168515110102
UR - http://link.springer.com/10.1134/S0020168515110102
TI - Proton conductivity of M x H3-x PX12O40 and M x H4-x SiX12O40 (M = Rb, Cs; X = W, Mo) acid salts of heteropolyacids
T2 - Inorganic Materials
AU - Safronova, E. Yu.
AU - Osipov, A K
AU - Baranchikov, A E
AU - Yaroslavtsev, A. B.
PY - 2015
DA - 2015/10/11
PB - Pleiades Publishing
SP - 1157-1162
IS - 11
VL - 51
SN - 0020-1685
SN - 1608-3172
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Safronova,
author = {E. Yu. Safronova and A K Osipov and A E Baranchikov and A. B. Yaroslavtsev},
title = {Proton conductivity of M x H3-x PX12O40 and M x H4-x SiX12O40 (M = Rb, Cs; X = W, Mo) acid salts of heteropolyacids},
journal = {Inorganic Materials},
year = {2015},
volume = {51},
publisher = {Pleiades Publishing},
month = {oct},
url = {http://link.springer.com/10.1134/S0020168515110102},
number = {11},
pages = {1157--1162},
doi = {10.1134/S0020168515110102}
}
Cite this
MLA
Copy
Safronova, E. Yu., et al. “Proton conductivity of M x H3-x PX12O40 and M x H4-x SiX12O40 (M = Rb, Cs; X = W, Mo) acid salts of heteropolyacids.” Inorganic Materials, vol. 51, no. 11, Oct. 2015, pp. 1157-1162. http://link.springer.com/10.1134/S0020168515110102.