Crystal structure of cis-[PdCl2 (CNMes)2 ]
Publication type: Journal Article
Publication date: 2016-07-01
scimago Q4
wos Q4
SJR: 0.211
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00224766, 15738779
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The interaction between PdCl2(CH3CN)2 and 2,4,6-Me3C6H2NC (MesNC) proceeds with the substitution of acetonitrile ligands and leads to the synthesis of a cis-[PdCl2(MesNC)2] complex. The structure of this compound is determined by single crystal X-ray diffraction (XRD). The complex has a slightly distorted square-planar structure of the metal center with two cis-positioned isocyanide ligands. In both CN isocyanide moieties the triple bonds have lengths similar to the lengths of the respective bonds in other isocyanide complexes. In the structure, the cis-[PdCl2(MesNC)2] complexes are bound by weak С–H∙∙∙Cl hydrogen bonds and π-stacking interactions.
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15
Total citations:
15
Citations from 2024:
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Kinzhalov M. A., Zolotarev A. A., Boyarskiy V. P. Crystal structure of cis-[PdCl2(CNMes)2] // Journal of Structural Chemistry. 2016. Vol. 57. No. 4. pp. 822-825.
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Kinzhalov M. A., Zolotarev A. A., Boyarskiy V. P. Crystal structure of cis-[PdCl2(CNMes)2] // Journal of Structural Chemistry. 2016. Vol. 57. No. 4. pp. 822-825.
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TY - JOUR
DO - 10.1134/S0022476616040302
UR - https://doi.org/10.1134/S0022476616040302
TI - Crystal structure of cis-[PdCl2(CNMes)2]
T2 - Journal of Structural Chemistry
AU - Kinzhalov, M A
AU - Zolotarev, A. A.
AU - Boyarskiy, V P
PY - 2016
DA - 2016/07/01
PB - Pleiades Publishing
SP - 822-825
IS - 4
VL - 57
SN - 0022-4766
SN - 1573-8779
ER -
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BibTex (up to 50 authors)
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@article{2016_Kinzhalov,
author = {M A Kinzhalov and A. A. Zolotarev and V P Boyarskiy},
title = {Crystal structure of cis-[PdCl2(CNMes)2]},
journal = {Journal of Structural Chemistry},
year = {2016},
volume = {57},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134/S0022476616040302},
number = {4},
pages = {822--825},
doi = {10.1134/S0022476616040302}
}
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MLA
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Kinzhalov, M. A., et al. “Crystal structure of cis-[PdCl2(CNMes)2].” Journal of Structural Chemistry, vol. 57, no. 4, Jul. 2016, pp. 822-825. https://doi.org/10.1134/S0022476616040302.
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