Complexes of Cobalt and Copper Halides Based on 1,3-Dimethylimidazolium-4-Carboxylate
Publication type: Journal Article
Publication date: 2019-10-01
scimago Q4
wos Q4
SJR: 0.211
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00224766, 15738779
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
In the interaction of norzooanemonin 1,3-dimethylimidazolium-4-carboxylate (1) with CuBr2, two types of crystals form: purple [Cu(L)2Br2][CuBr4][CuL4] (2) and light blue [CuL4][CuBr3] (3). In the reaction of 1 with CoCl2 in methanol, neutral complex Co(L)2Cl2 (4) forms. The thermal decomposition of complex 4 is studied. At the first stage of this decomposition, two equivalents of CO2 remove in a range 218–275 °C, and then a two-phase removal of two equivalents of L and the formation of CoCl2 occur.
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Shapovalov S. S. et al. Complexes of Cobalt and Copper Halides Based on 1,3-Dimethylimidazolium-4-Carboxylate // Journal of Structural Chemistry. 2019. Vol. 60. No. 10. pp. 1648-1654.
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Shapovalov S. S., Kolos A. V., Makhin A. P., Skabitskii I. V., Simonenko N. P., Minin V. V. Complexes of Cobalt and Copper Halides Based on 1,3-Dimethylimidazolium-4-Carboxylate // Journal of Structural Chemistry. 2019. Vol. 60. No. 10. pp. 1648-1654.
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TY - JOUR
DO - 10.1134/S002247661910010X
UR - https://doi.org/10.1134/S002247661910010X
TI - Complexes of Cobalt and Copper Halides Based on 1,3-Dimethylimidazolium-4-Carboxylate
T2 - Journal of Structural Chemistry
AU - Shapovalov, S S
AU - Kolos, A V
AU - Makhin, A P
AU - Skabitskii, I V
AU - Simonenko, N P
AU - Minin, V V
PY - 2019
DA - 2019/10/01
PB - Pleiades Publishing
SP - 1648-1654
IS - 10
VL - 60
SN - 0022-4766
SN - 1573-8779
ER -
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BibTex (up to 50 authors)
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@article{2019_Shapovalov,
author = {S S Shapovalov and A V Kolos and A P Makhin and I V Skabitskii and N P Simonenko and V V Minin},
title = {Complexes of Cobalt and Copper Halides Based on 1,3-Dimethylimidazolium-4-Carboxylate},
journal = {Journal of Structural Chemistry},
year = {2019},
volume = {60},
publisher = {Pleiades Publishing},
month = {oct},
url = {https://doi.org/10.1134/S002247661910010X},
number = {10},
pages = {1648--1654},
doi = {10.1134/S002247661910010X}
}
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MLA
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Shapovalov, S. S., et al. “Complexes of Cobalt and Copper Halides Based on 1,3-Dimethylimidazolium-4-Carboxylate.” Journal of Structural Chemistry, vol. 60, no. 10, Oct. 2019, pp. 1648-1654. https://doi.org/10.1134/S002247661910010X.