Influence of the nuclearity of copper(II) chloride complexes on their activity in catalytic C-Cl bond metathesis
E. N. Golubeva
1
,
V.I. Pergushov
1
,
A I Kokorin
2
,
D.I. Kochubey
3
,
V.V. Kriventsov
3
,
N A Zubareva
1
Publication type: Journal Article
Publication date: 2008-09-29
scimago Q3
wos Q4
SJR: 0.260
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Abstract
Catalytic systems containing mainly mononuclear (CuCl42−) or dinuclear (Cu2Cl62−) tributylbenzylammonium chlorocuprates are prepared by adsorption on silica surfaces of different structures (Aerosil and Silokhrom). Using ESR, XANES, and electronic spectroscopy, the CuCl42− ions are shown to be reduced rapidly under conditions of C-Cl bond metathesis, whereas the dinuclear chlorocuprates are relatively stable. A correlation between the number of copper ions in the chlorocuprate anion and its catalytic activity is established: the mononuclear complexes are several times more active than their dinuclear counterparts.
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Golubeva E. N. et al. Influence of the nuclearity of copper(II) chloride complexes on their activity in catalytic C-Cl bond metathesis // Kinetics and Catalysis. 2008. Vol. 49. No. 5. pp. 737-742.
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Golubeva E. N., Pergushov V., Kokorin A. I., Kochubey D., Kriventsov V., Zubareva N. A. Influence of the nuclearity of copper(II) chloride complexes on their activity in catalytic C-Cl bond metathesis // Kinetics and Catalysis. 2008. Vol. 49. No. 5. pp. 737-742.
Cite this
RIS
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TY - JOUR
DO - 10.1134/S0023158408050194
UR - https://doi.org/10.1134/S0023158408050194
TI - Influence of the nuclearity of copper(II) chloride complexes on their activity in catalytic C-Cl bond metathesis
T2 - Kinetics and Catalysis
AU - Golubeva, E. N.
AU - Pergushov, V.I.
AU - Kokorin, A I
AU - Kochubey, D.I.
AU - Kriventsov, V.V.
AU - Zubareva, N A
PY - 2008
DA - 2008/09/29
PB - Pleiades Publishing
SP - 737-742
IS - 5
VL - 49
SN - 0023-1584
SN - 1608-3210
ER -
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BibTex (up to 50 authors)
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@article{2008_Golubeva,
author = {E. N. Golubeva and V.I. Pergushov and A I Kokorin and D.I. Kochubey and V.V. Kriventsov and N A Zubareva},
title = {Influence of the nuclearity of copper(II) chloride complexes on their activity in catalytic C-Cl bond metathesis},
journal = {Kinetics and Catalysis},
year = {2008},
volume = {49},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134/S0023158408050194},
number = {5},
pages = {737--742},
doi = {10.1134/S0023158408050194}
}
Cite this
MLA
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Golubeva, E. N., et al. “Influence of the nuclearity of copper(II) chloride complexes on their activity in catalytic C-Cl bond metathesis.” Kinetics and Catalysis, vol. 49, no. 5, Sep. 2008, pp. 737-742. https://doi.org/10.1134/S0023158408050194.
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