Distinguishing between the homogeneous and heterogeneous mechanisms of catalysis in the Mizoroki-Heck and Suzuki-Miyaura reactions: Problems and prospects
Тип публикации: Journal Article
Дата публикации: 2012-11-24
scimago Q3
wos Q4
БС2
SJR: 0.260
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Краткое описание
This review presents a critical analysis of experimental methods used in distinguishing between the homogeneous and heterogeneous catalytic mechanisms in the Mizoroki-Heck and Suzuki-Miyaura reactions. The main problems arising in the interpretation of data obtained by these methods are discussed. It is demonstrated that it is necessary to take into account the dynamics of the interconversion of molecular, nanosized, and larger palladium species that is independent of the catalyst precursor type (dissolved or solid). The role of the in situ formation of colloidal palladium particles in the case of a supported catalyst precursor is considered.
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Schmidt A., Kurokhtina A. A. Distinguishing between the homogeneous and heterogeneous mechanisms of catalysis in the Mizoroki-Heck and Suzuki-Miyaura reactions: Problems and prospects // Kinetics and Catalysis. 2012. Vol. 53. No. 6. pp. 714-730.
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Schmidt A., Kurokhtina A. A. Distinguishing between the homogeneous and heterogeneous mechanisms of catalysis in the Mizoroki-Heck and Suzuki-Miyaura reactions: Problems and prospects // Kinetics and Catalysis. 2012. Vol. 53. No. 6. pp. 714-730.
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TY - JOUR
DO - 10.1134/S0023158412060109
UR - https://doi.org/10.1134/S0023158412060109
TI - Distinguishing between the homogeneous and heterogeneous mechanisms of catalysis in the Mizoroki-Heck and Suzuki-Miyaura reactions: Problems and prospects
T2 - Kinetics and Catalysis
AU - Schmidt, A.F.
AU - Kurokhtina, A A
PY - 2012
DA - 2012/11/24
PB - Pleiades Publishing
SP - 714-730
IS - 6
VL - 53
SN - 0023-1584
SN - 1608-3210
ER -
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BibTex (до 50 авторов)
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@article{2012_Schmidt,
author = {A.F. Schmidt and A A Kurokhtina},
title = {Distinguishing between the homogeneous and heterogeneous mechanisms of catalysis in the Mizoroki-Heck and Suzuki-Miyaura reactions: Problems and prospects},
journal = {Kinetics and Catalysis},
year = {2012},
volume = {53},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134/S0023158412060109},
number = {6},
pages = {714--730},
doi = {10.1134/S0023158412060109}
}
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MLA
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Schmidt, A.F., and A A Kurokhtina. “Distinguishing between the homogeneous and heterogeneous mechanisms of catalysis in the Mizoroki-Heck and Suzuki-Miyaura reactions: Problems and prospects.” Kinetics and Catalysis, vol. 53, no. 6, Nov. 2012, pp. 714-730. https://doi.org/10.1134/S0023158412060109.