Extraction of rare-earth elements by alkylated dibenzo-18-crown-6 and dicyclohexano-18-crown-6 from acid solutions
Тип публикации: Journal Article
Дата публикации: 2006-10-23
SCImago Q3
WOS Q4
БС2
SJR: 0.273
CiteScore: 3
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Краткое описание
The extraction of rare-earth elements (REE) by alkylated crown ethers (dibenzo-and dicyclohexano-18-crown 6; DB18C6 and DCH18C6) from acid solutions in the chloroform-water system is studied. The extraction of the REE with DCH18C6 and its alkylated derivatives in the presence of trichloroacetic acid (TCA) is far more efficient than the extraction with DB18C6 and its alkylated derivatives or when nitric or acetic acid is used instead of TCA. The distribution coefficients for the cerium metals are far higher than for the yttrium metals. The metal: crown ether ratio in the extracted complex in all cases is 1:1.
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Demin S. V. et al. Extraction of rare-earth elements by alkylated dibenzo-18-crown-6 and dicyclohexano-18-crown-6 from acid solutions // Russian Journal of Inorganic Chemistry. 2006. Vol. 51. No. 10. pp. 1678-1681.
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Demin S. V., Zhilov V. I., Tsivadze A. Y., Yakshin V. V., Vilkova O. N., Tsarenko N. A. Extraction of rare-earth elements by alkylated dibenzo-18-crown-6 and dicyclohexano-18-crown-6 from acid solutions // Russian Journal of Inorganic Chemistry. 2006. Vol. 51. No. 10. pp. 1678-1681.
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TY - JOUR
DO - 10.1134/S0036023606100275
UR - http://link.springer.com/10.1134/S0036023606100275
TI - Extraction of rare-earth elements by alkylated dibenzo-18-crown-6 and dicyclohexano-18-crown-6 from acid solutions
T2 - Russian Journal of Inorganic Chemistry
AU - Demin, S V
AU - Zhilov, V I
AU - Tsivadze, A. Yu.
AU - Yakshin, V. V.
AU - Vilkova, O N
AU - Tsarenko, N A
PY - 2006
DA - 2006/10/23
PB - Pleiades Publishing
SP - 1678-1681
IS - 10
VL - 51
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2006_Demin,
author = {S V Demin and V I Zhilov and A. Yu. Tsivadze and V. V. Yakshin and O N Vilkova and N A Tsarenko},
title = {Extraction of rare-earth elements by alkylated dibenzo-18-crown-6 and dicyclohexano-18-crown-6 from acid solutions},
journal = {Russian Journal of Inorganic Chemistry},
year = {2006},
volume = {51},
publisher = {Pleiades Publishing},
month = {oct},
url = {http://link.springer.com/10.1134/S0036023606100275},
number = {10},
pages = {1678--1681},
doi = {10.1134/S0036023606100275}
}
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MLA
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Demin, S. V., et al. “Extraction of rare-earth elements by alkylated dibenzo-18-crown-6 and dicyclohexano-18-crown-6 from acid solutions.” Russian Journal of Inorganic Chemistry, vol. 51, no. 10, Oct. 2006, pp. 1678-1681. http://link.springer.com/10.1134/S0036023606100275.
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