Synthesis, crystal structure, and vibrational spectrum of lithium N-(4'-benzo-15-crown-5)-5-bromo-2-hydroxyphenylaldiminatozinc perchlorate dihydrate
L Kh Minacheva
1
,
I. S. Ivanova
1
,
A V Dorokhov
1
,
A S Burlov
2
,
A. D. Garnovskii
2
,
V S Sergienko
1
,
Publication type: Journal Article
Publication date: 2007-03-01
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
The synthesis, the IR absorption spectrum, and X-ray diffraction analysis of the complex [ZnLi(L1)2(H2O)](ClO4) · H2O (I) (HL1 = N-(4′-benzo-15-crown-5)-5-bromo-2-hydroxyphenylaldimine) are described. The crystals of I are monoclinic, a = 19.840(4) Å, b = 13.947(3) Å, c = 19.956(4) Å, β = 117.06(3)°, V = 4917.4(17) Å3, Z = 4, space group P21/n, R = 0.0609 for 1409 reflections with I > 2σ(I). In the complex cation [ZnLi(L1)2(H2O)]+, the Zn atom is bound to a distorted tetrahedral array of two N atoms (av. Zn-N, 2.027(10) Å) and two O atoms (av. Zn-O, 1.8968(8) Å) of two deprotonated L1 ligands. The Li atom linked to the five ether oxygen atoms (av. Li-Oether, 2.254(3) Å) sits atop the benzo-15-crown-5 (B15C5) macrocyclic plane of one coordinated L1 ligand. The Li coordination is completed by water oxygen (Li-O(w1), 1.83(5) Å). The B15C5 cavity of the second coordinated ligand L1 is vacant.
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Minacheva L. Kh. et al. Synthesis, crystal structure, and vibrational spectrum of lithium N-(4'-benzo-15-crown-5)-5-bromo-2-hydroxyphenylaldiminatozinc perchlorate dihydrate // Russian Journal of Inorganic Chemistry. 2007. Vol. 52. No. 3. pp. 351-358.
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Minacheva L. Kh., Ivanova I. S., Dorokhov A. V., Burlov A. S., Garnovskii A. D., Sergienko V. S., Tsivadze A. Y. Synthesis, crystal structure, and vibrational spectrum of lithium N-(4'-benzo-15-crown-5)-5-bromo-2-hydroxyphenylaldiminatozinc perchlorate dihydrate // Russian Journal of Inorganic Chemistry. 2007. Vol. 52. No. 3. pp. 351-358.
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TY - JOUR
DO - 10.1134/S0036023607030102
UR - https://link.springer.com/10.1134/S0036023607030102
TI - Synthesis, crystal structure, and vibrational spectrum of lithium N-(4'-benzo-15-crown-5)-5-bromo-2-hydroxyphenylaldiminatozinc perchlorate dihydrate
T2 - Russian Journal of Inorganic Chemistry
AU - Minacheva, L Kh
AU - Ivanova, I. S.
AU - Dorokhov, A V
AU - Burlov, A S
AU - Garnovskii, A. D.
AU - Sergienko, V S
AU - Tsivadze, A. Yu.
PY - 2007
DA - 2007/03/01
PB - Pleiades Publishing
SP - 351-358
IS - 3
VL - 52
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2007_Minacheva,
author = {L Kh Minacheva and I. S. Ivanova and A V Dorokhov and A S Burlov and A. D. Garnovskii and V S Sergienko and A. Yu. Tsivadze},
title = {Synthesis, crystal structure, and vibrational spectrum of lithium N-(4'-benzo-15-crown-5)-5-bromo-2-hydroxyphenylaldiminatozinc perchlorate dihydrate},
journal = {Russian Journal of Inorganic Chemistry},
year = {2007},
volume = {52},
publisher = {Pleiades Publishing},
month = {mar},
url = {https://link.springer.com/10.1134/S0036023607030102},
number = {3},
pages = {351--358},
doi = {10.1134/S0036023607030102}
}
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MLA
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Minacheva, L. Kh., et al. “Synthesis, crystal structure, and vibrational spectrum of lithium N-(4'-benzo-15-crown-5)-5-bromo-2-hydroxyphenylaldiminatozinc perchlorate dihydrate.” Russian Journal of Inorganic Chemistry, vol. 52, no. 3, Mar. 2007, pp. 351-358. https://link.springer.com/10.1134/S0036023607030102.