Synthesis, structure, physicochemical properties, and solid-phase thermolysis of Co2Sm(Piv)7(2,4-Lut)2
M. A. Bykov
1
,
A L Emelina
1
,
E V Orlova
2
,
M. A. Kiskin
2
,
G.G. Aleksandrov
2
,
A S Bogomyakov
3
,
Zh V Dobrokhotova
2
,
V. M. Novotortsev
2
,
Publication type: Journal Article
Publication date: 2009-04-01
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Heterometallic pivalate Co2Sm(Piv)7(2,4-Lut)2 (1) was prepared for the first time and structurally characterized at 293 and 160 K. Antiferromagnetic exchange interactions are dominant in complex 1. This compound experiences a first-order phase transition within 210–260 K. A set of thermodynamic functions was obtained for this complex (Cp, HT0 - H1800, and ST0), and parameters were determined for solid-phase thermolysis where samarium cobaltate SmCoO3 is the only product.
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Bykov M. A. et al. Synthesis, structure, physicochemical properties, and solid-phase thermolysis of Co2Sm(Piv)7(2,4-Lut)2 // Russian Journal of Inorganic Chemistry. 2009. Vol. 54. No. 4. pp. 548-557.
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Bykov M. A., Emelina A. L., Orlova E. V., Kiskin M. A., Aleksandrov G., Bogomyakov A. S., Dobrokhotova Z. V., Novotortsev V. M., Eremenko I. L. Synthesis, structure, physicochemical properties, and solid-phase thermolysis of Co2Sm(Piv)7(2,4-Lut)2 // Russian Journal of Inorganic Chemistry. 2009. Vol. 54. No. 4. pp. 548-557.
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RIS
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TY - JOUR
DO - 10.1134/S003602360904010X
UR - https://doi.org/10.1134/S003602360904010X
TI - Synthesis, structure, physicochemical properties, and solid-phase thermolysis of Co2Sm(Piv)7(2,4-Lut)2
T2 - Russian Journal of Inorganic Chemistry
AU - Bykov, M. A.
AU - Emelina, A L
AU - Orlova, E V
AU - Kiskin, M. A.
AU - Aleksandrov, G.G.
AU - Bogomyakov, A S
AU - Dobrokhotova, Zh V
AU - Novotortsev, V. M.
AU - Eremenko, I. L.
PY - 2009
DA - 2009/04/01
PB - Pleiades Publishing
SP - 548-557
IS - 4
VL - 54
SN - 0036-0236
SN - 1531-8613
ER -
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BibTex (up to 50 authors)
Copy
@article{2009_Bykov,
author = {M. A. Bykov and A L Emelina and E V Orlova and M. A. Kiskin and G.G. Aleksandrov and A S Bogomyakov and Zh V Dobrokhotova and V. M. Novotortsev and I. L. Eremenko},
title = {Synthesis, structure, physicochemical properties, and solid-phase thermolysis of Co2Sm(Piv)7(2,4-Lut)2},
journal = {Russian Journal of Inorganic Chemistry},
year = {2009},
volume = {54},
publisher = {Pleiades Publishing},
month = {apr},
url = {https://doi.org/10.1134/S003602360904010X},
number = {4},
pages = {548--557},
doi = {10.1134/S003602360904010X}
}
Cite this
MLA
Copy
Bykov, M. A., et al. “Synthesis, structure, physicochemical properties, and solid-phase thermolysis of Co2Sm(Piv)7(2,4-Lut)2.” Russian Journal of Inorganic Chemistry, vol. 54, no. 4, Apr. 2009, pp. 548-557. https://doi.org/10.1134/S003602360904010X.