Russian Journal of Inorganic Chemistry

, volume 54 , issue 4 , pages 558-562

Syntheses and structures of Osmium(II) and Osmium(VI) meso-tetra(benzo-15- crown-5)porphyrinates according to the spectral data

Yu A Plachev ¹

A Yu Chernyadyev ¹

A. Yu. Tsivadze ¹

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Frumkin Institute of Physical Chemistry and electrochemistry, Russian Academy of Sciences, Moscow, Russia |

Publication type: Journal Article

Publication date: 2009-04-01

Pleiades Publishing

Russian Journal of Inorganic Chemistry

scimago Q3

wos Q4

SJR: 0.270

CiteScore: 3.0

Impact factor: 1.5

ISSN: 00360236, 15318613

DOI: 10.1134/S0036023609040111

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Inorganic Chemistry

Physical and Theoretical Chemistry

Materials Science (miscellaneous)

Abstract

The reaction of meso-tetra(benzo-15-crown-5)porphyrin (H2TCP) with the osmium carbonyl complex Os3(CO)12 yieds the corresponding osmium(II) porphyrinate OsTCP(CO). The oxidation of OsTCP(CO) with air oxygen and hydrogen peroxide in neutral and acidic media was studied. A preparative method for the synthesis of osmium(VI) meso-tetra(benzo-15-crown-5)porphyrinate (OsO2) TCP by the oxidation of OsTCP(CO) with 50% hydrogen peroxide in acetic acid was developed. The structures of new osmium porphyrinates were determined by IR, 1H NMR, and UV/Vis spectroscopies.

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Plachev Yu. A. et al. Syntheses and structures of Osmium(II) and Osmium(VI) meso-tetra(benzo-15- crown-5)porphyrinates according to the spectral data // Russian Journal of Inorganic Chemistry. 2009. Vol. 54. No. 4. pp. 558-562.

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Plachev Yu. A., Chernyadyev A. Yu., Tsivadze A. Y. Syntheses and structures of Osmium(II) and Osmium(VI) meso-tetra(benzo-15- crown-5)porphyrinates according to the spectral data // Russian Journal of Inorganic Chemistry. 2009. Vol. 54. No. 4. pp. 558-562.

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TY - JOUR

DO - 10.1134/S0036023609040111

UR - http://link.springer.com/10.1134/S0036023609040111

TI - Syntheses and structures of Osmium(II) and Osmium(VI) meso-tetra(benzo-15- crown-5)porphyrinates according to the spectral data

T2 - Russian Journal of Inorganic Chemistry

AU - Plachev, Yu A

AU - Chernyadyev, A Yu

AU - Tsivadze, A. Yu.

PY - 2009

DA - 2009/04/01

PB - Pleiades Publishing

SP - 558-562

IS - 4

VL - 54

SN - 0036-0236

SN - 1531-8613

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2009_Plachev,

author = {Yu A Plachev and A Yu Chernyadyev and A. Yu. Tsivadze},

title = {Syntheses and structures of Osmium(II) and Osmium(VI) meso-tetra(benzo-15- crown-5)porphyrinates according to the spectral data},

journal = {Russian Journal of Inorganic Chemistry},

year = {2009},

volume = {54},

publisher = {Pleiades Publishing},

month = {apr},

url = {http://link.springer.com/10.1134/S0036023609040111},

number = {4},

pages = {558--562},

doi = {10.1134/S0036023609040111}

}

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Plachev, Yu. A., et al. “Syntheses and structures of Osmium(II) and Osmium(VI) meso-tetra(benzo-15- crown-5)porphyrinates according to the spectral data.” Russian Journal of Inorganic Chemistry, vol. 54, no. 4, Apr. 2009, pp. 558-562. http://link.springer.com/10.1134/S0036023609040111.