Pleiades Publishing
Russian Journal of Inorganic Chemistry
,  volume 54 ,  issue 10 ,  pages 1571-1576

2-(diphenylphosphinylmethoxy)aniline: Synthesis, vibrational spectra, and crystal structure

Publication type: Journal Article
Publication date: 2009-10-12
Pleiades Publishing
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
The synthesis, vibrational spectra, and X-ray diffraction analysis results for 2-(diphenylphosphinylmethoxy) aniline, 2-[(C6H5)2P(O)OCH2]C6H4NH2(I), are described. The crystals are monoclinic: a = 18.4515(17) Å, b = 10.5421(12) Å, c = 17.897(2) Å, β = 104.479(8)°, V = 3370.7(6) Å3, Z = 8, space group P21/c, R = 0.0546 for 1770 reflections with I > 2σ(I). The unit cell contains two crystallographically independent molecules Ia and Ib joined by an N-H …O hydrogen bond between a hydrogen atom of the amino group of aniline in molecule Ia (Ib) and the phosphoryl oxygen atom of molecule Ib (Ia) (O…H 2.18 and 2.19 Å, N…O, 2.979(5) and 3.000(5) Å; NHO angle, 154° and 157°).

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Minacheva L. Kh. et al. 2-(diphenylphosphinylmethoxy)aniline: Synthesis, vibrational spectra, and crystal structure // Russian Journal of Inorganic Chemistry. 2009. Vol. 54. No. 10. pp. 1571-1576.
GOST all authors (up to 50) Copy
Minacheva L. Kh., Ivanova I. S., Baulin V. E., Pyatova E. N., Sergienko V. S., Tsivadze A. Y. 2-(diphenylphosphinylmethoxy)aniline: Synthesis, vibrational spectra, and crystal structure // Russian Journal of Inorganic Chemistry. 2009. Vol. 54. No. 10. pp. 1571-1576.
RIS |
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TY - JOUR
DO - 10.1134/S003602360910012X
UR - http://link.springer.com/10.1134/S003602360910012X
TI - 2-(diphenylphosphinylmethoxy)aniline: Synthesis, vibrational spectra, and crystal structure
T2 - Russian Journal of Inorganic Chemistry
AU - Minacheva, L Kh
AU - Ivanova, I. S.
AU - Baulin, V E
AU - Pyatova, E N
AU - Sergienko, V S
AU - Tsivadze, A. Yu.
PY - 2009
DA - 2009/10/12
PB - Pleiades Publishing
SP - 1571-1576
IS - 10
VL - 54
SN - 0036-0236
SN - 1531-8613
ER -
BibTex |
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@article{2009_Minacheva,
author = {L Kh Minacheva and I. S. Ivanova and V E Baulin and E N Pyatova and V S Sergienko and A. Yu. Tsivadze},
title = {2-(diphenylphosphinylmethoxy)aniline: Synthesis, vibrational spectra, and crystal structure},
journal = {Russian Journal of Inorganic Chemistry},
year = {2009},
volume = {54},
publisher = {Pleiades Publishing},
month = {oct},
url = {http://link.springer.com/10.1134/S003602360910012X},
number = {10},
pages = {1571--1576},
doi = {10.1134/S003602360910012X}
}
MLA
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Minacheva, L. Kh., et al. “2-(diphenylphosphinylmethoxy)aniline: Synthesis, vibrational spectra, and crystal structure.” Russian Journal of Inorganic Chemistry, vol. 54, no. 10, Oct. 2009, pp. 1571-1576. http://link.springer.com/10.1134/S003602360910012X.