Russian Journal of Inorganic Chemistry

, том 55 , издание 3 , страницы 347-354

Synthesis and structure of heteroleptic Triple-Decker neodymium, europium, holmium, erbium, and ytterbium crown phthalocyaninates

Тип публикации: Journal Article

Дата публикации: 2010-03-01

Pleiades Publishing

Russian Journal of Inorganic Chemistry

scimago Q3

wos Q4

white level БС2

SJR: 0.27

CiteScore: 3

Impact factor: 1.5

ISSN: 00360236, 15318613

DOI: 10.1134/S0036023610030083

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Inorganic Chemistry

Physical and Theoretical Chemistry

Materials Science (miscellaneous)

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Two series of heteroleptic crown-substituted tris(phthalocyaninate) complexes (Pc)Ln[(15C5)4Pc]Ln(Pc) and [(15C5)4Pc]Ln[(15C5)4Pc]Ln(Pc), where 15C5 is 15-crown-5, (Pc2−) is the phthalocyaninate dianion, Ln = Nd, Eu, Ho, Er, and Yb, were prepared by the reaction of tetra-15-crown-5-phthalocyanine H2[(15C5)4Pc] with the corresponding lanthanide acetylacetonates and lanthanum bis(phthalocyaninate) La(Pc)2, which was used as a phthalocyaninate dianion donor. The composition and structure of the synthesized complexes were confirmed by MALDI TOF mass spectrometry, UV-Vis absorption spectroscopy, and 1H NMR. Complete assignment of the proton resonance signals of the paramagnetic lanthanide complexes was based on analysis of lanthanide-induced shifts.

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Martynov A. G. et al. Synthesis and structure of heteroleptic Triple-Decker neodymium, europium, holmium, erbium, and ytterbium crown phthalocyaninates // Russian Journal of Inorganic Chemistry. 2010. Vol. 55. No. 3. pp. 347-354.

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Martynov A. G., Safonova E. A., Gorbunova Y. G., Tsivadze A. Y. Synthesis and structure of heteroleptic Triple-Decker neodymium, europium, holmium, erbium, and ytterbium crown phthalocyaninates // Russian Journal of Inorganic Chemistry. 2010. Vol. 55. No. 3. pp. 347-354.

RIS |

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TY - JOUR

DO - 10.1134/S0036023610030083

UR - http://link.springer.com/10.1134/S0036023610030083

TI - Synthesis and structure of heteroleptic Triple-Decker neodymium, europium, holmium, erbium, and ytterbium crown phthalocyaninates

T2 - Russian Journal of Inorganic Chemistry

AU - Martynov, A G

AU - Safonova, E A

AU - Gorbunova, Yu. G.

AU - Tsivadze, A. Yu.

PY - 2010

DA - 2010/03/01

PB - Pleiades Publishing

SP - 347-354

IS - 3

VL - 55

SN - 0036-0236

SN - 1531-8613

ER -

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@article{2010_Martynov,

author = {A G Martynov and E A Safonova and Yu. G. Gorbunova and A. Yu. Tsivadze},

title = {Synthesis and structure of heteroleptic Triple-Decker neodymium, europium, holmium, erbium, and ytterbium crown phthalocyaninates},

journal = {Russian Journal of Inorganic Chemistry},

year = {2010},

volume = {55},

publisher = {Pleiades Publishing},

month = {mar},

url = {http://link.springer.com/10.1134/S0036023610030083},

number = {3},

pages = {347--354},

doi = {10.1134/S0036023610030083}

}

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Martynov, A. G., et al. “Synthesis and structure of heteroleptic Triple-Decker neodymium, europium, holmium, erbium, and ytterbium crown phthalocyaninates.” Russian Journal of Inorganic Chemistry, vol. 55, no. 3, Mar. 2010, pp. 347-354. http://link.springer.com/10.1134/S0036023610030083.

Издатель

Pleiades Publishing

Журнал

Russian Journal of Inorganic Chemistry

scimago Q3

wos Q4

white level БС2

SJR

0.27

CiteScore

Impact factor

1.5