Thermal behavior of samarium binuclear pivalate and tris-pivalate
A L Emelina
1
,
Zh V Dobrokhotova
2
,
A A Sinelshchikova
1
,
Yu.A. Velikodnyi
1
,
I.G. Fomina
2
,
P S Koroteev
2
,
V. M. Novotortsev
2
,
Publication type: Journal Article
Publication date: 2010-11-03
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Kinetic analysis of the thermolysis of samarium pivalate [Sm2(μ2-OOCCMe3)4(OOCCMe3)2(HOOCCMe3)6] · HOOCCMe3 (1) was carried out (the input data were differential scanning calorimetry (DSC) and thermogravimetry data), and a mathematic model of the process was developed that allowed us to optimize (by calculation) the conditions for formation of {Sm(OOCCMe3)3}n (2) samarium tris-pivalate via thermal decomposition of complex 1. The results of the thermal study of samarium and gadolinium tris-pivalates in the temperature range of −50…+50°C are reported. Specific anomalies were found in the DSC curves and heat capacity versus temperature curves in the temperature range of 0–50°C.
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Total citations:
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Citations from 2024:
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GOST
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Emelina A. L. et al. Thermal behavior of samarium binuclear pivalate and tris-pivalate // Russian Journal of Inorganic Chemistry. 2010. Vol. 55. No. 11. pp. 1754-1761.
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Emelina A. L., Dobrokhotova Z. V., Sinelshchikova A. A., Velikodnyi Y., Fomina I., Koroteev P. S., Novotortsev V. M., Eremenko I. L. Thermal behavior of samarium binuclear pivalate and tris-pivalate // Russian Journal of Inorganic Chemistry. 2010. Vol. 55. No. 11. pp. 1754-1761.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S0036023610110124
UR - https://doi.org/10.1134/S0036023610110124
TI - Thermal behavior of samarium binuclear pivalate and tris-pivalate
T2 - Russian Journal of Inorganic Chemistry
AU - Emelina, A L
AU - Dobrokhotova, Zh V
AU - Sinelshchikova, A A
AU - Velikodnyi, Yu.A.
AU - Fomina, I.G.
AU - Koroteev, P S
AU - Novotortsev, V. M.
AU - Eremenko, I. L.
PY - 2010
DA - 2010/11/03
PB - Pleiades Publishing
SP - 1754-1761
IS - 11
VL - 55
SN - 0036-0236
SN - 1531-8613
ER -
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BibTex (up to 50 authors)
Copy
@article{2010_Emelina,
author = {A L Emelina and Zh V Dobrokhotova and A A Sinelshchikova and Yu.A. Velikodnyi and I.G. Fomina and P S Koroteev and V. M. Novotortsev and I. L. Eremenko},
title = {Thermal behavior of samarium binuclear pivalate and tris-pivalate},
journal = {Russian Journal of Inorganic Chemistry},
year = {2010},
volume = {55},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134/S0036023610110124},
number = {11},
pages = {1754--1761},
doi = {10.1134/S0036023610110124}
}
Cite this
MLA
Copy
Emelina, A. L., et al. “Thermal behavior of samarium binuclear pivalate and tris-pivalate.” Russian Journal of Inorganic Chemistry, vol. 55, no. 11, Nov. 2010, pp. 1754-1761. https://doi.org/10.1134/S0036023610110124.
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