Coprecipitation from aqueous solutions to prepare binary fluorides
P. P. Fedorov
1
,
S. V. Kuznetsov
1
,
M N Mayakova
1
,
V.V. Voronov
1
,
R P Ermakov
1
,
A E Baranchikov
2
,
V. V. Osiko
1
Publication type: Journal Article
Publication date: 2011-10-10
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
The synthesis of binary fluoride phases, specifically nanofluorides, by coprecipitation from aqueous solutions is considered in terms of phase equilibria. Phases have been precipitated in NaF-RF3 systems (where R stands for a rare-earth element), MF2-YF3 systems (where M = Ca, Sr, Ba), BaF2-ScF3, and CaF2-BaF2 systems. In the MF2-YF3 systems, unordered metastable congruently soluble phases are precipitated instead of ordered fluorite-like phases. In the BaF2-ScF3 system, the congruently soluble compound Ba3Sc2F12 is precipitated. In the NaF-RF3 systems, incongruently soluble metastable phases with a fluorite-like structure (for R = Er, Lu, Y) and the gagarinite structure (NaGdF4) are formed. In the CaF2-BaF2 system, intermediate phases have not been formed.
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Total citations:
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Citations from 2025:
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GOST
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Fedorov P. P. et al. Coprecipitation from aqueous solutions to prepare binary fluorides // Russian Journal of Inorganic Chemistry. 2011. Vol. 56. No. 10. pp. 1525-1531.
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Fedorov P. P., Kuznetsov S. V., Mayakova M. N., Voronov V., Ermakov R. P., Baranchikov A. E., Osiko V. V. Coprecipitation from aqueous solutions to prepare binary fluorides // Russian Journal of Inorganic Chemistry. 2011. Vol. 56. No. 10. pp. 1525-1531.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S003602361110007X
UR - http://link.springer.com/10.1134/S003602361110007X
TI - Coprecipitation from aqueous solutions to prepare binary fluorides
T2 - Russian Journal of Inorganic Chemistry
AU - Fedorov, P. P.
AU - Kuznetsov, S. V.
AU - Mayakova, M N
AU - Voronov, V.V.
AU - Ermakov, R P
AU - Baranchikov, A E
AU - Osiko, V. V.
PY - 2011
DA - 2011/10/10
PB - Pleiades Publishing
SP - 1525-1531
IS - 10
VL - 56
SN - 0036-0236
SN - 1531-8613
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2011_Fedorov,
author = {P. P. Fedorov and S. V. Kuznetsov and M N Mayakova and V.V. Voronov and R P Ermakov and A E Baranchikov and V. V. Osiko},
title = {Coprecipitation from aqueous solutions to prepare binary fluorides},
journal = {Russian Journal of Inorganic Chemistry},
year = {2011},
volume = {56},
publisher = {Pleiades Publishing},
month = {oct},
url = {http://link.springer.com/10.1134/S003602361110007X},
number = {10},
pages = {1525--1531},
doi = {10.1134/S003602361110007X}
}
Cite this
MLA
Copy
Fedorov, P. P., et al. “Coprecipitation from aqueous solutions to prepare binary fluorides.” Russian Journal of Inorganic Chemistry, vol. 56, no. 10, Oct. 2011, pp. 1525-1531. http://link.springer.com/10.1134/S003602361110007X.
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