Crystal and molecular structure and ion selective and complexing properties of 1,5-Bis[2-(dioxyphosphoryl-4-methoxy)phenoxy]-3-oxapentane dihydrate [(OH)2 (O)P(C6 H3 OCH3 )(OCH 2 CH2 )2 O(C6 H4 OCH 3 )P(O)(OH) 2 ]·2H2 O
V E Baulin
1
,
L Kh Minacheva
2
,
I. S. Ivanova
2
,
E N Pyatova
2
,
A.V. Churakov
2
,
V S Sergienko
2
,
2
Publication type: Journal Article
Publication date: 2012-06-13
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Ion selective and complexing properties of 1,5-bis[2-(dioxyphosphoryl-4-methoxy)phenoxy]-3-oxapentane dihydrate H4M2 · 2H2O (I) were described. X-ray diffraction analysis for compound I was performed. The crystals are orthorhombic, a = 7.9818(16) Å, b = 30.553(6) Å, c = 9.0559(17) Å, V = 2208.5(8) Å3, Z = 4, space group Pnma, R = 0.0500 over 1372 reflections with I > 2σ(I). In I, the H4M2 molecules are combined by hydrogen bonds (HB) with two crystallographically independent H2O(7) and H2O(8) molecules to give neutral H4M2 · 2H2O aggregates. The HB between the phosphoryl and hydroxyl oxygen atoms of the aggregates and the donor O(7)-H…O(8) HB give rise to a layered structure. Conclusions about the Cu(H2M2) compound structure were drawn based on the X-ray diffraction, DTA, and vibrational spectroscopy data.
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Russian Journal of Inorganic Chemistry
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Pleiades Publishing
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Baulin V. E. et al. Crystal and molecular structure and ion selective and complexing properties of 1,5-Bis[2-(dioxyphosphoryl-4-methoxy)phenoxy]-3-oxapentane dihydrate [(OH)2 (O)P(C6H3OCH3)(OCH 2CH2)2 O(C6H4OCH 3)P(O)(OH) 2]·2H2O // Russian Journal of Inorganic Chemistry. 2012. Vol. 57. No. 6. pp. 802-810.
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Baulin V. E., Minacheva L. Kh., Ivanova I. S., Pyatova E. N., Churakov A., Sergienko V. S., Tsivadze A. Y. Crystal and molecular structure and ion selective and complexing properties of 1,5-Bis[2-(dioxyphosphoryl-4-methoxy)phenoxy]-3-oxapentane dihydrate [(OH)2 (O)P(C6H3OCH3)(OCH 2CH2)2 O(C6H4OCH 3)P(O)(OH) 2]·2H2O // Russian Journal of Inorganic Chemistry. 2012. Vol. 57. No. 6. pp. 802-810.
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TY - JOUR
DO - 10.1134/S0036023612060046
UR - http://link.springer.com/10.1134/S0036023612060046
TI - Crystal and molecular structure and ion selective and complexing properties of 1,5-Bis[2-(dioxyphosphoryl-4-methoxy)phenoxy]-3-oxapentane dihydrate [(OH)2 (O)P(C6H3OCH3)(OCH 2CH2)2 O(C6H4OCH 3)P(O)(OH) 2]·2H2O
T2 - Russian Journal of Inorganic Chemistry
AU - Baulin, V E
AU - Minacheva, L Kh
AU - Ivanova, I. S.
AU - Pyatova, E N
AU - Churakov, A.V.
AU - Sergienko, V S
AU - Tsivadze, A. Yu.
PY - 2012
DA - 2012/06/13
PB - Pleiades Publishing
SP - 802-810
IS - 6
VL - 57
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2012_Baulin,
author = {V E Baulin and L Kh Minacheva and I. S. Ivanova and E N Pyatova and A.V. Churakov and V S Sergienko and A. Yu. Tsivadze},
title = {Crystal and molecular structure and ion selective and complexing properties of 1,5-Bis[2-(dioxyphosphoryl-4-methoxy)phenoxy]-3-oxapentane dihydrate [(OH)2 (O)P(C6H3OCH3)(OCH 2CH2)2 O(C6H4OCH 3)P(O)(OH) 2]·2H2O},
journal = {Russian Journal of Inorganic Chemistry},
year = {2012},
volume = {57},
publisher = {Pleiades Publishing},
month = {jun},
url = {http://link.springer.com/10.1134/S0036023612060046},
number = {6},
pages = {802--810},
doi = {10.1134/S0036023612060046}
}
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Baulin, V. E., et al. “Crystal and molecular structure and ion selective and complexing properties of 1,5-Bis[2-(dioxyphosphoryl-4-methoxy)phenoxy]-3-oxapentane dihydrate [(OH)2 (O)P(C6H3OCH3)(OCH 2CH2)2 O(C6H4OCH 3)P(O)(OH) 2]·2H2O.” Russian Journal of Inorganic Chemistry, vol. 57, no. 6, Jun. 2012, pp. 802-810. http://link.springer.com/10.1134/S0036023612060046.