XPS study of the electronic structure of heterometallic complexes [Fe 2 MO(O2 CCH3 )6 (H2 O) 3 ] · 3H2 O (M = Co, Ni)
T M Ivanova
1
,
K I Maslakov
2
,
R V Linko
3
,
I S Evstifeev
1
,
M. A. Kiskin
1
,
I N Shcherbakov
4
,
S. V. Savilov
2
,
V. V. Lunin
2
,
V. M. Novotortsev
1
,
Publication type: Journal Article
Publication date: 2014-07-24
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Heterometallic compounds of general formula [Fe 2 III MIIO(O2CR)6(H2O)3] · 3H2O (R = CH3, M = Co, Ni; R = CCl3, M = Co, Ni) have been studied by XPS. The compounds have been identified as high-spin complexes with metal atoms in oxidation states M(II) and M(III). Analysis of the XPS data revealed the tendency of the XPS pattern and magnetic parameters of molecules to change with a change in the electronic nature of metal atoms. The assignment is based on the degree of covalence of the M-O bond. In chloro-substituted heterocomplexes, electron density delocalization on the metal atoms with metal-to-ligand charge transfer through three bonds (M-O-C-C) is observed. The substitution in terminal groups leads to the change in the electron density distribution between the carboxylate and terminal groups.
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Ivanova T. M. et al. XPS study of the electronic structure of heterometallic complexes [Fe 2MO(O2CCH3)6(H2O) 3] · 3H2O (M = Co, Ni) // Russian Journal of Inorganic Chemistry. 2014. Vol. 59. No. 7. pp. 670-677.
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Ivanova T. M., Maslakov K. I., Linko R. V., Evstifeev I. S., Kiskin M. A., Shcherbakov I. N., Savilov S., Lunin V. V., Novotortsev V. M., Eremenko I. L. XPS study of the electronic structure of heterometallic complexes [Fe 2MO(O2CCH3)6(H2O) 3] · 3H2O (M = Co, Ni) // Russian Journal of Inorganic Chemistry. 2014. Vol. 59. No. 7. pp. 670-677.
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TY - JOUR
DO - 10.1134/S0036023614070067
UR - https://doi.org/10.1134/S0036023614070067
TI - XPS study of the electronic structure of heterometallic complexes [Fe 2MO(O2CCH3)6(H2O) 3] · 3H2O (M = Co, Ni)
T2 - Russian Journal of Inorganic Chemistry
AU - Ivanova, T M
AU - Maslakov, K I
AU - Linko, R V
AU - Evstifeev, I S
AU - Kiskin, M. A.
AU - Shcherbakov, I N
AU - Savilov, S. V.
AU - Lunin, V. V.
AU - Novotortsev, V. M.
AU - Eremenko, I. L.
PY - 2014
DA - 2014/07/24
PB - Pleiades Publishing
SP - 670-677
IS - 7
VL - 59
SN - 0036-0236
SN - 1531-8613
ER -
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BibTex (up to 50 authors)
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@article{2014_Ivanova,
author = {T M Ivanova and K I Maslakov and R V Linko and I S Evstifeev and M. A. Kiskin and I N Shcherbakov and S. V. Savilov and V. V. Lunin and V. M. Novotortsev and I. L. Eremenko},
title = {XPS study of the electronic structure of heterometallic complexes [Fe 2MO(O2CCH3)6(H2O) 3] · 3H2O (M = Co, Ni)},
journal = {Russian Journal of Inorganic Chemistry},
year = {2014},
volume = {59},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134/S0036023614070067},
number = {7},
pages = {670--677},
doi = {10.1134/S0036023614070067}
}
Cite this
MLA
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Ivanova, T. M., et al. “XPS study of the electronic structure of heterometallic complexes [Fe 2MO(O2CCH3)6(H2O) 3] · 3H2O (M = Co, Ni).” Russian Journal of Inorganic Chemistry, vol. 59, no. 7, Jul. 2014, pp. 670-677. https://doi.org/10.1134/S0036023614070067.