Synthesis and photoelectrochemical properties of cyclometallated ruthenium(II) complex
S A Kurzeev
1
,
A V Medvedko
1
,
V A Grinberg
2
,
S A Kozyukhin
3, 4
,
V V Emets
2
,
A A Sadovnikov
3
,
A E Baranchikov
3
,
V.K. Ivanov
3, 4
,
V.N. Andreev
2
,
E A Nizhnikovskii
5
3
5
Joint Scientific Council of the Presidium of the RAS for Integrated Problems in Physics, Chemistry, and Biology, Moscow, Russia
|
Publication type: Journal Article
Publication date: 2014-07-23
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
A new ruthenium complex, (4-carboxy-1,10-phenantroline-7-carboxylate)(4,7-dicarboxy-1,10-phenantroline)(2-phenylpyridino-2C,N) ruthenium(II), was obtained for the application as a sensitizer in photoelectrochemical converters (PECC). Electrochemical and spectral characteristics of the compound were studied. It was found that the illumination of PECC with AM 1.5 100 mW/cm2 solar spectrum simulator provides short circuit current density of 3.9 mA cm−2 and broken circuit voltage of 0.47 V. PECC efficiency is 1.4% at fillfactor 76%. The lifetimes of charge carriers (electrons) and their transit time determined by modulation spectroscopy were found to be 28 and 4 ms, respectively.
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Kurzeev S. A. et al. Synthesis and photoelectrochemical properties of cyclometallated ruthenium(II) complex // Russian Journal of Inorganic Chemistry. 2014. Vol. 59. No. 7. pp. 658-664.
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Kurzeev S. A., Medvedko A. V., Grinberg V. A., Kozyukhin S. A., Emets V. V., Sadovnikov A. A., Baranchikov A. E., Ivanov V., Andreev V., Nizhnikovskii E. A. Synthesis and photoelectrochemical properties of cyclometallated ruthenium(II) complex // Russian Journal of Inorganic Chemistry. 2014. Vol. 59. No. 7. pp. 658-664.
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TY - JOUR
DO - 10.1134/S0036023614070110
UR - http://link.springer.com/10.1134/S0036023614070110
TI - Synthesis and photoelectrochemical properties of cyclometallated ruthenium(II) complex
T2 - Russian Journal of Inorganic Chemistry
AU - Kurzeev, S A
AU - Medvedko, A V
AU - Grinberg, V A
AU - Kozyukhin, S A
AU - Emets, V V
AU - Sadovnikov, A A
AU - Baranchikov, A E
AU - Ivanov, V.K.
AU - Andreev, V.N.
AU - Nizhnikovskii, E A
PY - 2014
DA - 2014/07/23
PB - Pleiades Publishing
SP - 658-664
IS - 7
VL - 59
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2014_Kurzeev,
author = {S A Kurzeev and A V Medvedko and V A Grinberg and S A Kozyukhin and V V Emets and A A Sadovnikov and A E Baranchikov and V.K. Ivanov and V.N. Andreev and E A Nizhnikovskii},
title = {Synthesis and photoelectrochemical properties of cyclometallated ruthenium(II) complex},
journal = {Russian Journal of Inorganic Chemistry},
year = {2014},
volume = {59},
publisher = {Pleiades Publishing},
month = {jul},
url = {http://link.springer.com/10.1134/S0036023614070110},
number = {7},
pages = {658--664},
doi = {10.1134/S0036023614070110}
}
Cite this
MLA
Copy
Kurzeev, S. A., et al. “Synthesis and photoelectrochemical properties of cyclometallated ruthenium(II) complex.” Russian Journal of Inorganic Chemistry, vol. 59, no. 7, Jul. 2014, pp. 658-664. http://link.springer.com/10.1134/S0036023614070110.