Phase diagram of the NaF–CaF2 system and the electrical conductivity of a CaF2-based solid solution
P. P. Fedorov
1, 2
,
M N Mayakova
1
,
S. V. Kuznetsov
1
,
V. A. Maslov
1
,
N. I. Sorokin
3
,
A E Baranchikov
4
,
V.K. Ivanov
4
,
A A Pynenkov
2
,
M A Uslamina
2
,
K N Nishchev
2
Тип публикации: Journal Article
Дата публикации: 2016-11-14
scimago Q3
wos Q4
БС2
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Краткое описание
The phase diagram of the NaF–CaF2 system was studied by thermal analysis and X-ray powder diffraction analysis with the determination of the chemical composition. The system was found to be of the eutectic type. A narrow range of the existence of solid solution Ca1–xNaxF2–x was established. The NaF solubility reaches a maximal value of x = 0.035 at 1200 ± 50°C (the temperature at which there is a diffuse phase transition in fluorite). At 920 ± 25°C, the NaF solubility reaches a minimum (<0.4 mol %) and increases again to 2.2 ± 0.2 mol % at a eutectic temperature (818°C). The ionic conductivity increases by three orders of magnitude after adding NaF to CaF2.
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Fedorov P. P. et al. Phase diagram of the NaF–CaF2 system and the electrical conductivity of a CaF2-based solid solution // Russian Journal of Inorganic Chemistry. 2016. Vol. 61. No. 11. pp. 1472-1478.
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Fedorov P. P., Mayakova M. N., Kuznetsov S. V., Maslov V. A., Sorokin N. I., Baranchikov A. E., Ivanov V., Pynenkov A. A., Uslamina M. A., Nishchev K. N. Phase diagram of the NaF–CaF2 system and the electrical conductivity of a CaF2-based solid solution // Russian Journal of Inorganic Chemistry. 2016. Vol. 61. No. 11. pp. 1472-1478.
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TY - JOUR
DO - 10.1134/S003602361611005X
UR - http://link.springer.com/10.1134/S003602361611005X
TI - Phase diagram of the NaF–CaF2 system and the electrical conductivity of a CaF2-based solid solution
T2 - Russian Journal of Inorganic Chemistry
AU - Fedorov, P. P.
AU - Mayakova, M N
AU - Kuznetsov, S. V.
AU - Maslov, V. A.
AU - Sorokin, N. I.
AU - Baranchikov, A E
AU - Ivanov, V.K.
AU - Pynenkov, A A
AU - Uslamina, M A
AU - Nishchev, K N
PY - 2016
DA - 2016/11/14
PB - Pleiades Publishing
SP - 1472-1478
IS - 11
VL - 61
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2016_Fedorov,
author = {P. P. Fedorov and M N Mayakova and S. V. Kuznetsov and V. A. Maslov and N. I. Sorokin and A E Baranchikov and V.K. Ivanov and A A Pynenkov and M A Uslamina and K N Nishchev},
title = {Phase diagram of the NaF–CaF2 system and the electrical conductivity of a CaF2-based solid solution},
journal = {Russian Journal of Inorganic Chemistry},
year = {2016},
volume = {61},
publisher = {Pleiades Publishing},
month = {nov},
url = {http://link.springer.com/10.1134/S003602361611005X},
number = {11},
pages = {1472--1478},
doi = {10.1134/S003602361611005X}
}
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MLA
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Fedorov, P. P., et al. “Phase diagram of the NaF–CaF2 system and the electrical conductivity of a CaF2-based solid solution.” Russian Journal of Inorganic Chemistry, vol. 61, no. 11, Nov. 2016, pp. 1472-1478. http://link.springer.com/10.1134/S003602361611005X.