Vaporization Thermodynamics of Polymeric Cadmium Pivalate
D.B. Kayumova
1
,
I. P. MALKEROVA
1
,
M. A. Shmelev
1
,
A. A. Sidorov
1
,
I. L. Eremenko
1
,
A. S. ALIKHANYAN
1
Publication type: Journal Article
Publication date: 2019-01-01
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
The vaporization of cadmium pivalate CdPiv2 with a polymeric structure was studied by the Knudsen effusion mass spectrometry of the gas phase. The sublimation of this complex was found to be congruent and to be accompanied by thermal dissociation with the formation of metal atoms and organic compounds due to its polymeric character. The standard enthalpies of vaporization were found, and the standard formation enthalpy of condensed cadmium pivalate was calculated. Highly volatile cadmium compounds could be synthesized via the introduction of additional ligands able to saturate the coordination sphere of the central atom.
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Kayumova D. et al. Vaporization Thermodynamics of Polymeric Cadmium Pivalate // Russian Journal of Inorganic Chemistry. 2019. Vol. 64. No. 1. pp. 125-129.
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Kayumova D., MALKEROVA I. P., Shmelev M. A., Sidorov A. A., Eremenko I. L., ALIKHANYAN A. S. Vaporization Thermodynamics of Polymeric Cadmium Pivalate // Russian Journal of Inorganic Chemistry. 2019. Vol. 64. No. 1. pp. 125-129.
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RIS
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TY - JOUR
DO - 10.1134/S0036023619010121
UR - https://doi.org/10.1134/S0036023619010121
TI - Vaporization Thermodynamics of Polymeric Cadmium Pivalate
T2 - Russian Journal of Inorganic Chemistry
AU - Kayumova, D.B.
AU - MALKEROVA, I. P.
AU - Shmelev, M. A.
AU - Sidorov, A. A.
AU - Eremenko, I. L.
AU - ALIKHANYAN, A. S.
PY - 2019
DA - 2019/01/01
PB - Pleiades Publishing
SP - 125-129
IS - 1
VL - 64
SN - 0036-0236
SN - 1531-8613
ER -
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BibTex (up to 50 authors)
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@article{2019_Kayumova,
author = {D.B. Kayumova and I. P. MALKEROVA and M. A. Shmelev and A. A. Sidorov and I. L. Eremenko and A. S. ALIKHANYAN},
title = {Vaporization Thermodynamics of Polymeric Cadmium Pivalate},
journal = {Russian Journal of Inorganic Chemistry},
year = {2019},
volume = {64},
publisher = {Pleiades Publishing},
month = {jan},
url = {https://doi.org/10.1134/S0036023619010121},
number = {1},
pages = {125--129},
doi = {10.1134/S0036023619010121}
}
Cite this
MLA
Copy
Kayumova, D.B., et al. “Vaporization Thermodynamics of Polymeric Cadmium Pivalate.” Russian Journal of Inorganic Chemistry, vol. 64, no. 1, Jan. 2019, pp. 125-129. https://doi.org/10.1134/S0036023619010121.