Oxidation of Iron Complex with NHC Ligand with Molecular Iodine
Publication type: Journal Article
Publication date: 2019-11-01
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Complex (η5-C5H5)2Fe2(CO)4 (I) reacts with 1,3-dimethylimidazolium-2-carboxylate Me2ImCO2 to give asymmetric binuclear carbene iron complex (η5-C5H5)2Fe2(CO)3(Me2Im) (II) (Me2Im = 1,3-dimethylimidazol-2-ylidene). The oxidation of compound II with elemental iodine proceeds via two mechanisms, symmetrical and asymmetrical, to form four products: (η5-C5H5Fe(CO)2(Me2Im)I (III), (η5-C5H5)Fe(CO)2I (IV), (η5-C5H5Fe(CO)2(Me2Im)I3 (V), and ferrocene (VI). In each case, two pairs of reaction products have formed, two of which include NHC ligand: neutral iron(III) complex and ionic complex V. Optimal synthesis conditions to obtain preferably one of these complexes have been found. Geometry and transition state energy of supposed reaction mechanism have been calculated by quantum chemistry methods.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
|
|
|
Organometallics
1 publication, 100%
|
|
|
1
|
Publishers
|
1
|
|
|
American Chemical Society (ACS)
1 publication, 100%
|
|
|
1
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
1
Total citations:
1
Citations from 2024:
0
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Shapovalov S. S. et al. Oxidation of Iron Complex with NHC Ligand with Molecular Iodine // Russian Journal of Inorganic Chemistry. 2019. Vol. 64. No. 11. pp. 1418-1423.
GOST all authors (up to 50)
Copy
Shapovalov S. S., Tikhonova O. G., Skabitskii I. V., Kolos A. V., Sakharov S. G., Torubaev Yu. V. Oxidation of Iron Complex with NHC Ligand with Molecular Iodine // Russian Journal of Inorganic Chemistry. 2019. Vol. 64. No. 11. pp. 1418-1423.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S0036023619110184
UR - http://link.springer.com/10.1134/S0036023619110184
TI - Oxidation of Iron Complex with NHC Ligand with Molecular Iodine
T2 - Russian Journal of Inorganic Chemistry
AU - Shapovalov, S S
AU - Tikhonova, O G
AU - Skabitskii, I V
AU - Kolos, A V
AU - Sakharov, S G
AU - Torubaev, Yu V
PY - 2019
DA - 2019/11/01
PB - Pleiades Publishing
SP - 1418-1423
IS - 11
VL - 64
SN - 0036-0236
SN - 1531-8613
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Shapovalov,
author = {S S Shapovalov and O G Tikhonova and I V Skabitskii and A V Kolos and S G Sakharov and Yu V Torubaev},
title = {Oxidation of Iron Complex with NHC Ligand with Molecular Iodine},
journal = {Russian Journal of Inorganic Chemistry},
year = {2019},
volume = {64},
publisher = {Pleiades Publishing},
month = {nov},
url = {http://link.springer.com/10.1134/S0036023619110184},
number = {11},
pages = {1418--1423},
doi = {10.1134/S0036023619110184}
}
Cite this
MLA
Copy
Shapovalov, S. S., et al. “Oxidation of Iron Complex with NHC Ligand with Molecular Iodine.” Russian Journal of Inorganic Chemistry, vol. 64, no. 11, Nov. 2019, pp. 1418-1423. http://link.springer.com/10.1134/S0036023619110184.