Methylviologen Bromobismuthates
Publication type: Journal Article
Publication date: 2021-02-20
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
New methylviologen (MV2+) bromobismuthate [MV]3[BiBr6]2 · 2H2O (I) isostructural to the well-known chlorobismuthate [MV]3[BiCl6]2 · 2H2O has been prepared from an aqueous solution and cha-racterized by X-ray diffraction. The reaction between I and concentrated HBr leads to the formation of acidic methylviologen bromobismuthate-bromide [H3O]2[MV][BiBr6]Br · 4H2O (II) and a minor impurity of bromobismuthate tribromide [MV]3[Bi2Br9][Br3]3 (III). The acidic bromobismuthate of ethylviologen (EtV2+) [H3O][EtV][BiBr6] · 1.34H2O (IV) formed under similar conditions has another composition. Thermal decomposition of II yields single-phase [MV][BiBr5], which has a low optical band gap. The electrochemical characteristics of I and related iodobismuthate [MV]3[Bi2I11]I have been compared.
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10
Total citations:
10
Citations from 2024:
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(10%)
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GOST
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Buikin P. A. et al. Methylviologen Bromobismuthates // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 2. pp. 133-138.
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Buikin P. A., Ilyukhin A. B., Laurinavichyute V. K., Kotov V. Yu. Methylviologen Bromobismuthates // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 2. pp. 133-138.
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RIS
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TY - JOUR
DO - 10.1134/S0036023621020042
UR - http://link.springer.com/10.1134/S0036023621020042
TI - Methylviologen Bromobismuthates
T2 - Russian Journal of Inorganic Chemistry
AU - Buikin, P A
AU - Ilyukhin, A. B.
AU - Laurinavichyute, V K
AU - Kotov, V Yu
PY - 2021
DA - 2021/02/20
PB - Pleiades Publishing
SP - 133-138
IS - 2
VL - 66
SN - 0036-0236
SN - 1531-8613
ER -
Cite this
BibTex (up to 50 authors)
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@article{2021_Buikin,
author = {P A Buikin and A. B. Ilyukhin and V K Laurinavichyute and V Yu Kotov},
title = {Methylviologen Bromobismuthates},
journal = {Russian Journal of Inorganic Chemistry},
year = {2021},
volume = {66},
publisher = {Pleiades Publishing},
month = {feb},
url = {http://link.springer.com/10.1134/S0036023621020042},
number = {2},
pages = {133--138},
doi = {10.1134/S0036023621020042}
}
Cite this
MLA
Copy
Buikin, P. A., et al. “Methylviologen Bromobismuthates.” Russian Journal of Inorganic Chemistry, vol. 66, no. 2, Feb. 2021, pp. 133-138. http://link.springer.com/10.1134/S0036023621020042.
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