Effect of Initial CoII Salts on the Composition and Structure of Cs–CoII Dimethylmalonates
Publication type: Journal Article
Publication date: 2021-02-20
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Abstract The coordination compounds of cobalt(II) {[Cs 2 Co(H 2 O) 4 (Me 2 Mal) 2 ] · H 2 O} n ( 1 ) and {[Cs 8 Co 36 (H 2 O) 34 (OH) 20 (Me 2 Mal) 30 )] · 40H 2 O} n ( 2 ) (Me 2 Mal 2– is the dimethylmalonic acid dianion) have been synthesized by varying the initial cobalt(II) salt (CoCl 2 · 6H 2 O and Co(OAc) 2 · 4H 2 O, respectively) in the reaction with cesium dimethylmalonate (reagent ratio, 1 : 2). X-ray diffraction shows that a crystal of complex 1 is built of cobalt(II) dimethylmalonate anionic layers spaced apart by aquated cesium cations, and a crystal of complex 2 is composed of 36-nuclear spherical anions with cobalt(II) atoms, cesium cations, and solvated and coordinated water molecules.
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Zorina-Tikhonova E. N. et al. Effect of Initial CoII Salts on the Composition and Structure of Cs–CoII Dimethylmalonates // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 2. pp. 179-186.
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Zorina-Tikhonova E. N., Matyukhina A. K., Aleksandrov G., Kiskin M. A., Sidorov A. A., Eremenko I. L. Effect of Initial CoII Salts on the Composition and Structure of Cs–CoII Dimethylmalonates // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 2. pp. 179-186.
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RIS
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TY - JOUR
DO - 10.1134/S0036023621020212
UR - https://doi.org/10.1134/S0036023621020212
TI - Effect of Initial CoII Salts on the Composition and Structure of Cs–CoII Dimethylmalonates
T2 - Russian Journal of Inorganic Chemistry
AU - Zorina-Tikhonova, E. N.
AU - Matyukhina, A K
AU - Aleksandrov, G.G.
AU - Kiskin, M. A.
AU - Sidorov, A. A.
AU - Eremenko, I. L.
PY - 2021
DA - 2021/02/20
PB - Pleiades Publishing
SP - 179-186
IS - 2
VL - 66
SN - 0036-0236
SN - 1531-8613
ER -
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BibTex (up to 50 authors)
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@article{2021_Zorina-Tikhonova,
author = {E. N. Zorina-Tikhonova and A K Matyukhina and G.G. Aleksandrov and M. A. Kiskin and A. A. Sidorov and I. L. Eremenko},
title = {Effect of Initial CoII Salts on the Composition and Structure of Cs–CoII Dimethylmalonates},
journal = {Russian Journal of Inorganic Chemistry},
year = {2021},
volume = {66},
publisher = {Pleiades Publishing},
month = {feb},
url = {https://doi.org/10.1134/S0036023621020212},
number = {2},
pages = {179--186},
doi = {10.1134/S0036023621020212}
}
Cite this
MLA
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Zorina-Tikhonova, E. N., et al. “Effect of Initial CoII Salts on the Composition and Structure of Cs–CoII Dimethylmalonates.” Russian Journal of Inorganic Chemistry, vol. 66, no. 2, Feb. 2021, pp. 179-186. https://doi.org/10.1134/S0036023621020212.