SiO2–TiO2 Binary Aerogels: A Small-Angle Scattering Study
A E Baranchikov
1
,
G P Kopitsa
2, 3
,
Kh E Yorov
1
,
N A Sipyagina
4
,
S.A. Lermontov
4
,
A A Pavlova
2, 5
,
S Yu Kottsov
1
,
V. M. Garamus
6
,
V Ryukhtin
7
,
1
2
3
4
Тип публикации: Journal Article
Дата публикации: 2021-06-29
scimago Q3
wos Q4
БС2
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Краткое описание
Structural analysis in the range of characteristic sizes from 1 nm to ~1.5 µm was performed for SiO2–TiO2 aerogels prepared in supercritical CO2, isopropanol, hexafluoroisopropanol, or methyl-tert-butyl ether using small-angle X-ray scattering and neutron scattering complementary methods. A two-level model that accounts for scattering by individual inhomogeneities and their aggregates, which have fractal properties, satisfactorily describes the aerogel structures over the entire range of scales. It is shown for the first time that the titania concentration is the key factor in the small-angle neutron and X-ray scattering by SiO2–TiO2 aerogels. The phase composition of an aerogel does not significantly affect the aerogel structure in the range of scales from 1 nm to ~1.5 µm, as probed by small-angle X-ray and neutron scattering.
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Baranchikov A. E. et al. SiO2–TiO2 Binary Aerogels: A Small-Angle Scattering Study // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 6. pp. 874-882.
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Baranchikov A. E., Kopitsa G. P., Yorov Kh. E., Sipyagina N. A., Lermontov S., Pavlova A. A., Kottsov S. Yu., Garamus V. M., Ryukhtin V., Ivanov V. SiO2–TiO2 Binary Aerogels: A Small-Angle Scattering Study // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 6. pp. 874-882.
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TY - JOUR
DO - 10.1134/S003602362106005X
UR - https://link.springer.com/10.1134/S003602362106005X
TI - SiO2–TiO2 Binary Aerogels: A Small-Angle Scattering Study
T2 - Russian Journal of Inorganic Chemistry
AU - Baranchikov, A E
AU - Kopitsa, G P
AU - Yorov, Kh E
AU - Sipyagina, N A
AU - Lermontov, S.A.
AU - Pavlova, A A
AU - Kottsov, S Yu
AU - Garamus, V. M.
AU - Ryukhtin, V
AU - Ivanov, V.K.
PY - 2021
DA - 2021/06/29
PB - Pleiades Publishing
SP - 874-882
IS - 6
VL - 66
SN - 0036-0236
SN - 1531-8613
ER -
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@article{2021_Baranchikov,
author = {A E Baranchikov and G P Kopitsa and Kh E Yorov and N A Sipyagina and S.A. Lermontov and A A Pavlova and S Yu Kottsov and V. M. Garamus and V Ryukhtin and V.K. Ivanov},
title = {SiO2–TiO2 Binary Aerogels: A Small-Angle Scattering Study},
journal = {Russian Journal of Inorganic Chemistry},
year = {2021},
volume = {66},
publisher = {Pleiades Publishing},
month = {jun},
url = {https://link.springer.com/10.1134/S003602362106005X},
number = {6},
pages = {874--882},
doi = {10.1134/S003602362106005X}
}
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MLA
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Baranchikov, A. E., et al. “SiO2–TiO2 Binary Aerogels: A Small-Angle Scattering Study.” Russian Journal of Inorganic Chemistry, vol. 66, no. 6, Jun. 2021, pp. 874-882. https://link.springer.com/10.1134/S003602362106005X.