Russian Journal of Inorganic Chemistry, volume 66, issue 9, pages 1380-1389

Characteristic Features of Fixation of Ammonia by Copper(II), Nickel(II), and Cobalt(II) Ions in Pivalates

Publication typeJournal Article
Publication date2021-09-21
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor2.1
ISSN00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
The reaction of adduct Cu2(OOCBut)4(thf)2 with polynuclear nickel(II) pivalate (prepared from NiCl2, HOOCBut, and KOH) or cobalt(II) pivalate (prepared by thermolysis of Co(II) acetate with excess acid at 160°C) in THF with a large excess of aqueous ammonia at room temperature leads to the formation of the mononuclear molecular complex Cu(OOCBut)2(NH3)2, the ionic complex [Ni(NH3)6](OOCBut)2, and unusual mixed-valence trinuclear complex {CoII(OOCBut)2(NH3)2[(µ-OH)CoIII(NH3)5]2}(OOCBut)4(H2O)2. The products were investigated by chemical analysis, X-ray diffraction, and IR spectroscopy.
Metrics
Share
Cite this
GOST |
Cite this
GOST Copy
Nefedov S., Eremenko I. L. Characteristic Features of Fixation of Ammonia by Copper(II), Nickel(II), and Cobalt(II) Ions in Pivalates // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 9. pp. 1380-1389.
GOST all authors (up to 50) Copy
Nefedov S., Eremenko I. L. Characteristic Features of Fixation of Ammonia by Copper(II), Nickel(II), and Cobalt(II) Ions in Pivalates // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 9. pp. 1380-1389.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1134/S0036023621090084
UR - https://doi.org/10.1134%2FS0036023621090084
TI - Characteristic Features of Fixation of Ammonia by Copper(II), Nickel(II), and Cobalt(II) Ions in Pivalates
T2 - Russian Journal of Inorganic Chemistry
AU - Nefedov, S.E.
AU - Eremenko, I. L.
PY - 2021
DA - 2021/09/21 00:00:00
PB - Pleiades Publishing
SP - 1380-1389
IS - 9
VL - 66
SN - 0036-0236
SN - 1531-8613
ER -
BibTex |
Cite this
BibTex Copy
@article{2021_Nefedov
author = {S.E. Nefedov and I. L. Eremenko},
title = {Characteristic Features of Fixation of Ammonia by Copper(II), Nickel(II), and Cobalt(II) Ions in Pivalates},
journal = {Russian Journal of Inorganic Chemistry},
year = {2021},
volume = {66},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134%2FS0036023621090084},
number = {9},
pages = {1380--1389},
doi = {10.1134/S0036023621090084}
}
MLA
Cite this
MLA Copy
Nefedov, S.E., and I. L. Eremenko. “Characteristic Features of Fixation of Ammonia by Copper(II), Nickel(II), and Cobalt(II) Ions in Pivalates.” Russian Journal of Inorganic Chemistry, vol. 66, no. 9, Sep. 2021, pp. 1380-1389. https://doi.org/10.1134%2FS0036023621090084.
Found error?
Profiles