On the Thermal Decomposition of Cerium(IV) Hydrogen Phosphate Ce(PO4 )(HPO4 )0.5 (H2 O)0.5
T.O. Kozlova
1
,
A E Baranchikov
1
,
K V Birichevskaya
1
,
D. A. KOZLOV
1, 2
,
N P Simonenko
1
,
A. V. Gavrikov
1
,
M A Teplonogova
1, 2
,
Publication type: Journal Article
Publication date: 2021-11-18
scimago Q3
wos Q4
SJR: 0.270
CiteScore: 3.0
Impact factor: 1.5
ISSN: 00360236, 15318613
Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Abstract
Cerium(IV) hydrogen phosphate Ce(PO4)(HPO4)0.5(H2O)0.5 has been prepared by hydrothermal treatment of gels obtained by hydrolysis of cerium-containing phosphoric acid solutions. The obtained compound and the products of its heating in a wide temperature range have been analyzed by X-ray powder diffraction analysis, IR spectroscopy, mass spectrometry of gaseous thermolysis products, and scanning electron microscopy. Thermal decomposition of the compound at temperature up to 1200°С has been refined. In particular, it has been shown that crystalline cerium(III) phosphate (CePO4) forms upon heating of Ce(PO4)(HPO4)0.5(H2O)0.5 in air even at 600°C.
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Kozlova T. et al. On the Thermal Decomposition of Cerium(IV) Hydrogen Phosphate Ce(PO4)(HPO4)0.5(H2O)0.5 // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 11. pp. 1624-1632.
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Kozlova T., Baranchikov A. E., Birichevskaya K. V., KOZLOV D. A., Simonenko N. P., Gavrikov A. V., Teplonogova M. A., Ivanov V. On the Thermal Decomposition of Cerium(IV) Hydrogen Phosphate Ce(PO4)(HPO4)0.5(H2O)0.5 // Russian Journal of Inorganic Chemistry. 2021. Vol. 66. No. 11. pp. 1624-1632.
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TY - JOUR
DO - 10.1134/S0036023621110139
UR - https://link.springer.com/10.1134/S0036023621110139
TI - On the Thermal Decomposition of Cerium(IV) Hydrogen Phosphate Ce(PO4)(HPO4)0.5(H2O)0.5
T2 - Russian Journal of Inorganic Chemistry
AU - Kozlova, T.O.
AU - Baranchikov, A E
AU - Birichevskaya, K V
AU - KOZLOV, D. A.
AU - Simonenko, N P
AU - Gavrikov, A. V.
AU - Teplonogova, M A
AU - Ivanov, V.K.
PY - 2021
DA - 2021/11/18
PB - Pleiades Publishing
SP - 1624-1632
IS - 11
VL - 66
SN - 0036-0236
SN - 1531-8613
ER -
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BibTex (up to 50 authors)
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@article{2021_Kozlova,
author = {T.O. Kozlova and A E Baranchikov and K V Birichevskaya and D. A. KOZLOV and N P Simonenko and A. V. Gavrikov and M A Teplonogova and V.K. Ivanov},
title = {On the Thermal Decomposition of Cerium(IV) Hydrogen Phosphate Ce(PO4)(HPO4)0.5(H2O)0.5},
journal = {Russian Journal of Inorganic Chemistry},
year = {2021},
volume = {66},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://link.springer.com/10.1134/S0036023621110139},
number = {11},
pages = {1624--1632},
doi = {10.1134/S0036023621110139}
}
Cite this
MLA
Copy
Kozlova, T.O., et al. “On the Thermal Decomposition of Cerium(IV) Hydrogen Phosphate Ce(PO4)(HPO4)0.5(H2O)0.5.” Russian Journal of Inorganic Chemistry, vol. 66, no. 11, Nov. 2021, pp. 1624-1632. https://link.springer.com/10.1134/S0036023621110139.