volume 90 issue 9 pages 1903-1908

Mechanism of the anodic dissolution of gold in solutions of 6-alkyl-1,5-diazabicyclo[3.1.0]hexanes

M D Vedenyapina 1, 2
V. V. Kuznetsov 1
N N Makhova 1
A A Vedenyapin 1, 2
Publication typeJournal Article
Publication date2016-08-11
scimago Q4
wos Q4
SJR0.204
CiteScore1.2
Impact factor0.8
ISSN00360244, 1531863X
Physical and Theoretical Chemistry
Abstract
The electrochemical corrosion of gold in solutions of 6,6-dimethyl-1,5-diazabicyclo[3.1.0]hexane (I) and 6-methyl-1,5-diazabicyclo[3.1.0]hexane (II) on a gold electrode is studied via cyclic voltammetry. It is shown that the galvanostatic electrolysis of weakly basic aqueous solutions of I and II on gold anodes results in the corrosion of Au electrodes, probably with the formation of organic complexes of gold that are reduced to form a gold mirror on the inner surface of an electrochemical cell during electrolysis. A mechanism is proposed for the investigated processes.
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Vedenyapina M. D. et al. Mechanism of the anodic dissolution of gold in solutions of 6-alkyl-1,5-diazabicyclo[3.1.0]hexanes // Russian Journal of Physical Chemistry A. 2016. Vol. 90. No. 9. pp. 1903-1908.
GOST all authors (up to 50) Copy
Vedenyapina M. D., Kuznetsov V. V., Makhova N. N., Vedenyapin A. A. Mechanism of the anodic dissolution of gold in solutions of 6-alkyl-1,5-diazabicyclo[3.1.0]hexanes // Russian Journal of Physical Chemistry A. 2016. Vol. 90. No. 9. pp. 1903-1908.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S0036024416090284
UR - https://doi.org/10.1134/S0036024416090284
TI - Mechanism of the anodic dissolution of gold in solutions of 6-alkyl-1,5-diazabicyclo[3.1.0]hexanes
T2 - Russian Journal of Physical Chemistry A
AU - Vedenyapina, M D
AU - Kuznetsov, V. V.
AU - Makhova, N N
AU - Vedenyapin, A A
PY - 2016
DA - 2016/08/11
PB - Pleiades Publishing
SP - 1903-1908
IS - 9
VL - 90
SN - 0036-0244
SN - 1531-863X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2016_Vedenyapina,
author = {M D Vedenyapina and V. V. Kuznetsov and N N Makhova and A A Vedenyapin},
title = {Mechanism of the anodic dissolution of gold in solutions of 6-alkyl-1,5-diazabicyclo[3.1.0]hexanes},
journal = {Russian Journal of Physical Chemistry A},
year = {2016},
volume = {90},
publisher = {Pleiades Publishing},
month = {aug},
url = {https://doi.org/10.1134/S0036024416090284},
number = {9},
pages = {1903--1908},
doi = {10.1134/S0036024416090284}
}
MLA
Cite this
MLA Copy
Vedenyapina, M. D., et al. “Mechanism of the anodic dissolution of gold in solutions of 6-alkyl-1,5-diazabicyclo[3.1.0]hexanes.” Russian Journal of Physical Chemistry A, vol. 90, no. 9, Aug. 2016, pp. 1903-1908. https://doi.org/10.1134/S0036024416090284.