Russian Journal of Physical Chemistry A

, том 90 , издание 9 , страницы 1903-1908

Mechanism of the anodic dissolution of gold in solutions of 6-alkyl-1,5-diazabicyclo[3.1.0]hexanes

M D Vedenyapina ^{1, 2}

V. V. Kuznetsov ¹

N N Makhova ¹

A A Vedenyapin ^{1, 2}

Скрыть аффилиации авторов Показать аффилиации авторов: 2 аффилиации

Zelinsky Institute of Organic chemistry, Russian Academy of Sciences, Moscow, Russia |

Moscow Technological Institute, Moscow, Russia |

Тип публикации: Journal Article

Дата публикации: 2016-08-11

Pleiades Publishing

Russian Journal of Physical Chemistry A

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SJR: 0.204

CiteScore: 1.2

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ISSN: 00360244, 1531863X

DOI: 10.1134/S0036024416090284

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Physical and Theoretical Chemistry

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The electrochemical corrosion of gold in solutions of 6,6-dimethyl-1,5-diazabicyclo[3.1.0]hexane (I) and 6-methyl-1,5-diazabicyclo[3.1.0]hexane (II) on a gold electrode is studied via cyclic voltammetry. It is shown that the galvanostatic electrolysis of weakly basic aqueous solutions of I and II on gold anodes results in the corrosion of Au electrodes, probably with the formation of organic complexes of gold that are reduced to form a gold mirror on the inner surface of an electrochemical cell during electrolysis. A mechanism is proposed for the investigated processes.

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Институт органической химии им. Н.Д. Зелинского РАН

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Russian Chemical Bulletin	Russian Chemical Bulletin, 6, 66.67% Russian Chemical Bulletin 6 публикаций, 66.67%
Russian Journal of Physical Chemistry A	Russian Journal of Physical Chemistry A, 1, 11.11% Russian Journal of Physical Chemistry A 1 публикация, 11.11%
Mendeleev Communications	Mendeleev Communications, 1, 11.11% Mendeleev Communications 1 публикация, 11.11%
Russian Journal of Organic Chemistry	Russian Journal of Organic Chemistry, 1, 11.11% Russian Journal of Organic Chemistry 1 публикация, 11.11%
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Springer Nature	Springer Nature, 6, 66.67% Springer Nature 6 публикаций, 66.67%
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Vedenyapina M. D. et al. Mechanism of the anodic dissolution of gold in solutions of 6-alkyl-1,5-diazabicyclo[3.1.0]hexanes // Russian Journal of Physical Chemistry A. 2016. Vol. 90. No. 9. pp. 1903-1908.

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Vedenyapina M. D., Kuznetsov V. V., Makhova N. N., Vedenyapin A. A. Mechanism of the anodic dissolution of gold in solutions of 6-alkyl-1,5-diazabicyclo[3.1.0]hexanes // Russian Journal of Physical Chemistry A. 2016. Vol. 90. No. 9. pp. 1903-1908.

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TY - JOUR

DO - 10.1134/S0036024416090284

UR - https://doi.org/10.1134/S0036024416090284

TI - Mechanism of the anodic dissolution of gold in solutions of 6-alkyl-1,5-diazabicyclo[3.1.0]hexanes

T2 - Russian Journal of Physical Chemistry A

AU - Vedenyapina, M D

AU - Kuznetsov, V. V.

AU - Makhova, N N

AU - Vedenyapin, A A

PY - 2016

DA - 2016/08/11

PB - Pleiades Publishing

SP - 1903-1908

IS - 9

VL - 90

SN - 0036-0244

SN - 1531-863X

ER -

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@article{2016_Vedenyapina,

author = {M D Vedenyapina and V. V. Kuznetsov and N N Makhova and A A Vedenyapin},

title = {Mechanism of the anodic dissolution of gold in solutions of 6-alkyl-1,5-diazabicyclo[3.1.0]hexanes},

journal = {Russian Journal of Physical Chemistry A},

year = {2016},

volume = {90},

publisher = {Pleiades Publishing},

month = {aug},

url = {https://doi.org/10.1134/S0036024416090284},

number = {9},

pages = {1903--1908},

doi = {10.1134/S0036024416090284}

}

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Vedenyapina, M. D., et al. “Mechanism of the anodic dissolution of gold in solutions of 6-alkyl-1,5-diazabicyclo[3.1.0]hexanes.” Russian Journal of Physical Chemistry A, vol. 90, no. 9, Aug. 2016, pp. 1903-1908. https://doi.org/10.1134/S0036024416090284.