Structure of ruthenium(II) complexes with coproporphyrin I tetraethyl ester
S A Zverev
1, 2
,
S. V. Andreev
1, 3
,
I A Zamilatskov
1, 2
,
N M Kurochkina
1
,
V S Tyurin
1
,
I N Senchikhin
1
,
G.V Ponomarev
4
,
D R Erzina
1, 2
,
V. V. Chernyshev
1, 5
3
Rospotrebnadzor Research Institute of Disinfectology, Moscow, Russia
|
Publication type: Journal Article
Publication date: 2017-07-15
scimago Q4
wos Q4
SJR: 0.204
CiteScore: 1.2
Impact factor: 0.8
ISSN: 00360244, 1531863X
Physical and Theoretical Chemistry
Abstract
The reaction between coproporphyrin I tetraethyl ester and ruthenium(II) dodecacarbonyl in toluene is investigated. The formation of two different products, complexes 2 and 3 of ruthenium(II) with coproporphyrin I tetraethyl ester, studied by means of mass spectrometry, electronic absorption spectroscopy, NMR, X-ray diffraction, and thermogravimetric analysis, is revealed. Structures are proposed for the products, of which (2) is a monocarbonyl complex of ruthenium(II) porphyrin that exists as a coordination polymer formed owing to intermolecular axial bonding between the oxygen atoms of carboethoxyl groups and ruthenium(II). The structure proposed for second product (3) is in the form of the corresponding monomer of a monocarbonyl complex of ruthenium(II) porphyrin. It is established that polymeric complex 2 transforms into monomeric complex 3 when it is heating in pyridine.
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Zverev S. A. et al. Structure of ruthenium(II) complexes with coproporphyrin I tetraethyl ester // Russian Journal of Physical Chemistry A. 2017. Vol. 91. No. 8. pp. 1462-1467.
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Zverev S. A., Andreev S. V., Zamilatskov I. A., Kurochkina N. M., Tyurin V. S., Senchikhin I. N., Ponomarev G., Erzina D. R., Chernyshev V. V. Structure of ruthenium(II) complexes with coproporphyrin I tetraethyl ester // Russian Journal of Physical Chemistry A. 2017. Vol. 91. No. 8. pp. 1462-1467.
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TY - JOUR
DO - 10.1134/S0036024417080386
UR - http://link.springer.com/10.1134/S0036024417080386
TI - Structure of ruthenium(II) complexes with coproporphyrin I tetraethyl ester
T2 - Russian Journal of Physical Chemistry A
AU - Zverev, S A
AU - Andreev, S. V.
AU - Zamilatskov, I A
AU - Kurochkina, N M
AU - Tyurin, V S
AU - Senchikhin, I N
AU - Ponomarev, G.V
AU - Erzina, D R
AU - Chernyshev, V. V.
PY - 2017
DA - 2017/07/15
PB - Pleiades Publishing
SP - 1462-1467
IS - 8
VL - 91
SN - 0036-0244
SN - 1531-863X
ER -
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BibTex (up to 50 authors)
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@article{2017_Zverev,
author = {S A Zverev and S. V. Andreev and I A Zamilatskov and N M Kurochkina and V S Tyurin and I N Senchikhin and G.V Ponomarev and D R Erzina and V. V. Chernyshev},
title = {Structure of ruthenium(II) complexes with coproporphyrin I tetraethyl ester},
journal = {Russian Journal of Physical Chemistry A},
year = {2017},
volume = {91},
publisher = {Pleiades Publishing},
month = {jul},
url = {http://link.springer.com/10.1134/S0036024417080386},
number = {8},
pages = {1462--1467},
doi = {10.1134/S0036024417080386}
}
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MLA
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Zverev, S. A., et al. “Structure of ruthenium(II) complexes with coproporphyrin I tetraethyl ester.” Russian Journal of Physical Chemistry A, vol. 91, no. 8, Jul. 2017, pp. 1462-1467. http://link.springer.com/10.1134/S0036024417080386.