Intermolecular interactions governing solubilization in micelles of poly(alkylene oxide) surfactants
Publication type: Journal Article
Publication date: 2007-04-01
scimago Q3
wos Q4
SJR: 0.244
CiteScore: 1.9
Impact factor: 1.1
ISSN: 0965545X, 15556107, 17571820
Materials Chemistry
Polymers and Plastics
Abstract
Partition coefficients for 39 low-molecular-mass compounds between water and micelles of an ethylene oxide-propylene oxide block copolymer (Pluronic P85) and the monolauryl ether of poly(ethylene oxide) (Brij 35) have been measured by the methods of fluorescence spectroscopy, fluorescence anisotropy, and dialysis kinetics. The tested compounds include aromatic hydrocarbons, phenols, naphthols, xanthene dyes, anthracycline antibiotics, and porphyrins. The multifactor analysis of the partition coefficients in terms of the linear free-energy relationships has been performed. It has been shown that the H-donating ability of compounds facilitates their solubilization in Pluronic micelles and has no effect on solubilization in micelles of monolauryl ether of poly(ethylene oxide). This difference indicates that, when solubilization occurs in Pluronic micelles, the compounds under study appear in a hydrophobic core composed of poly(propylene oxide) blocks.
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Bugrin V. S. et al. Intermolecular interactions governing solubilization in micelles of poly(alkylene oxide) surfactants // Polymer Science - Series A. 2007. Vol. 49. No. 4. pp. 463-472.
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Bugrin V. S., Kozlov M. Yu., Baskin I. I., Melik-Nubarov N. Intermolecular interactions governing solubilization in micelles of poly(alkylene oxide) surfactants // Polymer Science - Series A. 2007. Vol. 49. No. 4. pp. 463-472.
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TY - JOUR
DO - 10.1134/S0965545X07040141
UR - http://link.springer.com/10.1134/S0965545X07040141
TI - Intermolecular interactions governing solubilization in micelles of poly(alkylene oxide) surfactants
T2 - Polymer Science - Series A
AU - Bugrin, V S
AU - Kozlov, M Yu
AU - Baskin, I I
AU - Melik-Nubarov, N.S.
PY - 2007
DA - 2007/04/01
PB - Pleiades Publishing
SP - 463-472
IS - 4
VL - 49
SN - 0965-545X
SN - 1555-6107
SN - 1757-1820
ER -
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BibTex (up to 50 authors)
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@article{2007_Bugrin,
author = {V S Bugrin and M Yu Kozlov and I I Baskin and N.S. Melik-Nubarov},
title = {Intermolecular interactions governing solubilization in micelles of poly(alkylene oxide) surfactants},
journal = {Polymer Science - Series A},
year = {2007},
volume = {49},
publisher = {Pleiades Publishing},
month = {apr},
url = {http://link.springer.com/10.1134/S0965545X07040141},
number = {4},
pages = {463--472},
doi = {10.1134/S0965545X07040141}
}
Cite this
MLA
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Bugrin, V. S., et al. “Intermolecular interactions governing solubilization in micelles of poly(alkylene oxide) surfactants.” Polymer Science - Series A, vol. 49, no. 4, Apr. 2007, pp. 463-472. http://link.springer.com/10.1134/S0965545X07040141.
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