volume 56 issue 5 pages 614-622

Water sorption on and water diffusion in chitin and chitosan

Publication typeJournal Article
Publication date2014-09-15
scimago Q3
wos Q4
SJR0.244
CiteScore1.9
Impact factor1.1
ISSN0965545X, 15556107, 17571820
Materials Chemistry
Polymers and Plastics
Abstract
The kinetics of the sorption of water vapor on powders of crab-shell chitin and chitosan are studied via the methods of static sorption, thermography, and X-ray structural analysis. Sorption isotherms are obtained in the range of humidity from 10 to 95%. S-Shaped water-sorption isotherms observed for all chitin and chitosan samples are approximated via superpositioning of Langmuir and Flory-Huggins isotherms. The water-polysaccharide interaction parameters and the maximum sorption capacities of water located in chitin and chitosan are determined. The cluster integral is calculated, and the moisture values corresponding to water-cluster formation are determined. The water-diffusion coefficients are determined, and the effective activation energies of water diffusion are estimated: 70 kJ/mol in chitosan and 60 kJ/mol in chitin. The data on the concentration dependences of the coefficients of diffusion of water in the powdered chitin and chitosan are summarized.
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GOST Copy
Chalykh A. et al. Water sorption on and water diffusion in chitin and chitosan // Polymer Science - Series A. 2014. Vol. 56. No. 5. pp. 614-622.
GOST all authors (up to 50) Copy
Chalykh A., Petrova T. F., Khasbiullin R. R., Ozerin A. N. Water sorption on and water diffusion in chitin and chitosan // Polymer Science - Series A. 2014. Vol. 56. No. 5. pp. 614-622.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S0965545X14050034
UR - https://doi.org/10.1134/S0965545X14050034
TI - Water sorption on and water diffusion in chitin and chitosan
T2 - Polymer Science - Series A
AU - Chalykh, A.E.
AU - Petrova, T F
AU - Khasbiullin, R R
AU - Ozerin, A. N.
PY - 2014
DA - 2014/09/15
PB - Pleiades Publishing
SP - 614-622
IS - 5
VL - 56
SN - 0965-545X
SN - 1555-6107
SN - 1757-1820
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2014_Chalykh,
author = {A.E. Chalykh and T F Petrova and R R Khasbiullin and A. N. Ozerin},
title = {Water sorption on and water diffusion in chitin and chitosan},
journal = {Polymer Science - Series A},
year = {2014},
volume = {56},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134/S0965545X14050034},
number = {5},
pages = {614--622},
doi = {10.1134/S0965545X14050034}
}
MLA
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MLA Copy
Chalykh, A.E., et al. “Water sorption on and water diffusion in chitin and chitosan.” Polymer Science - Series A, vol. 56, no. 5, Sep. 2014, pp. 614-622. https://doi.org/10.1134/S0965545X14050034.