The role of carbon support morphology in the formation of catalytic layer of solid-polymer fuel cell
Publication type: Journal Article
Publication date: 2014-09-12
scimago Q4
wos Q4
SJR: 0.236
CiteScore: 1.9
Impact factor: 0.8
ISSN: 10231935, 16083342
Electrochemistry
Abstract
The Pt/C catalysts with similar morphology of active catalytic phase (platinum nanoparticles), which were deposited on the supports with different types of carbon structures (Vulkan XC-72 carbon black, Taunit carbon tubes, and Timrex HSAG-300 carbon support with graphite structure), were fabricated by the method of electrochemical dispersion. The effect of the carbon structure type on the electrocatalytic properties of Pt/C catalysts was studied in their operation in the three-electrode cell and in-service in the membrane-electrode assembly of air-hydrogen solid-polymer fuel cell. The Pt/C catalyst based on the Vulkan XC-72 carbon support showed the best performance. The anisotropic shape of Taunit carbon nanotubes and the microstructure of Timrex HSAG-300 carbon support do not allow us to form a catalytic layer with a large active platinum surface area and a structure, which provides an effective ionic transport and mass exchange near the platinum surface.
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Total citations:
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Citations from 2024:
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(12.5%)
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Smirnova N. V. et al. The role of carbon support morphology in the formation of catalytic layer of solid-polymer fuel cell // Russian Journal of Electrochemistry. 2014. Vol. 50. No. 9. pp. 899-903.
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Smirnova N. V., Kuriganova A. B., Novikova K. S., Gerasimova E. V. The role of carbon support morphology in the formation of catalytic layer of solid-polymer fuel cell // Russian Journal of Electrochemistry. 2014. Vol. 50. No. 9. pp. 899-903.
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RIS
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TY - JOUR
DO - 10.1134/s1023193514070143
UR - https://doi.org/10.1134/s1023193514070143
TI - The role of carbon support morphology in the formation of catalytic layer of solid-polymer fuel cell
T2 - Russian Journal of Electrochemistry
AU - Smirnova, N. V.
AU - Kuriganova, A B
AU - Novikova, K S
AU - Gerasimova, E V
PY - 2014
DA - 2014/09/12
PB - Pleiades Publishing
SP - 899-903
IS - 9
VL - 50
SN - 1023-1935
SN - 1608-3342
ER -
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BibTex (up to 50 authors)
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@article{2014_Smirnova,
author = {N. V. Smirnova and A B Kuriganova and K S Novikova and E V Gerasimova},
title = {The role of carbon support morphology in the formation of catalytic layer of solid-polymer fuel cell},
journal = {Russian Journal of Electrochemistry},
year = {2014},
volume = {50},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134/s1023193514070143},
number = {9},
pages = {899--903},
doi = {10.1134/s1023193514070143}
}
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MLA
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Smirnova, N. V., et al. “The role of carbon support morphology in the formation of catalytic layer of solid-polymer fuel cell.” Russian Journal of Electrochemistry, vol. 50, no. 9, Sep. 2014, pp. 899-903. https://doi.org/10.1134/s1023193514070143.