The Effect of Electrode Potential on the Conductivity of Polymer Complexes of Nickel with Salen Ligands
Publication type: Journal Article
Publication date: 2019-04-01
scimago Q4
wos Q4
SJR: 0.236
CiteScore: 1.9
Impact factor: 0.8
ISSN: 10231935, 16083342
Electrochemistry
Abstract
The influence of the electrode potential on the electric conductivity of polymer complexes of nickel with salen-type ligands (where salen is N,N′-ethylene-bis(salicylideneimine)) differing by substituents in ligand′s benzene ring is studied in the course of measuring cyclic voltammograms. The highest electron conductivity is observed for the film of poly[N,N′-ethylene-bis(3-methoxysalicylideneiminato) nickel(II)] (poly[Ni(CH3OSalen)]) in 1 M LiPF6 solution in the ethylene carbonate-diethylcarbonate mixture (EC: DEC = 1: 1). Poly[N,N′-ethylene-bis(3-methyl-salicyleneiminato) nickel(II)] (or poly[Ni(CH3Salen)]) was found to have the widest potential range of electronic conductivity. Conditions are selected for synthesizing films from solutions of the corresponding monomers in 1 M LiPF6 EC: DEC electrolyte. The electrode potential intervals suitable for the use of poly[Ni(CH3Salen)] as the buffer interlayer between the aluminum substrate and the cathode mass in lithium-ion batteries for protecting the latter against overcharge are found.
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Total citations:
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Citations from 2025:
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(18.52%)
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Beletskii E. V. et al. The Effect of Electrode Potential on the Conductivity of Polymer Complexes of Nickel with Salen Ligands // Russian Journal of Electrochemistry. 2019. Vol. 55. No. 4. pp. 339-345.
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Beletskii E. V., Volosatova Yu. A., Eliseeva S. N., Levin O. V. The Effect of Electrode Potential on the Conductivity of Polymer Complexes of Nickel with Salen Ligands // Russian Journal of Electrochemistry. 2019. Vol. 55. No. 4. pp. 339-345.
Cite this
RIS
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TY - JOUR
DO - 10.1134/S1023193519030030
UR - https://doi.org/10.1134/S1023193519030030
TI - The Effect of Electrode Potential on the Conductivity of Polymer Complexes of Nickel with Salen Ligands
T2 - Russian Journal of Electrochemistry
AU - Beletskii, E V
AU - Volosatova, Yu A
AU - Eliseeva, S. N.
AU - Levin, O. V.
PY - 2019
DA - 2019/04/01
PB - Pleiades Publishing
SP - 339-345
IS - 4
VL - 55
SN - 1023-1935
SN - 1608-3342
ER -
Cite this
BibTex (up to 50 authors)
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@article{2019_Beletskii,
author = {E V Beletskii and Yu A Volosatova and S. N. Eliseeva and O. V. Levin},
title = {The Effect of Electrode Potential on the Conductivity of Polymer Complexes of Nickel with Salen Ligands},
journal = {Russian Journal of Electrochemistry},
year = {2019},
volume = {55},
publisher = {Pleiades Publishing},
month = {apr},
url = {https://doi.org/10.1134/S1023193519030030},
number = {4},
pages = {339--345},
doi = {10.1134/S1023193519030030}
}
Cite this
MLA
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Beletskii, E. V., et al. “The Effect of Electrode Potential on the Conductivity of Polymer Complexes of Nickel with Salen Ligands.” Russian Journal of Electrochemistry, vol. 55, no. 4, Apr. 2019, pp. 339-345. https://doi.org/10.1134/S1023193519030030.