On the size effect in nanocrystalline cerium dioxide: Is the Tsunekawa model correct?
Тип публикации: Journal Article
Дата публикации: 2014-09-01
scimago Q4
wos Q4
БС4
SJR: 0.165
CiteScore: 0.8
Impact factor: 0.4
ISSN: 10274510, 18197094
Surfaces, Coatings and Films
Краткое описание
Nanocrystalline cerium-dioxide samples with different coherent-scattering region sizes are analyzed by advanced techniques, specifically, small-angle neutron scattering, X-ray and neutron diffraction, and spectrometry of the chemical shift in the characteristic X-ray lines. The obtained data confirm the presence of the size effect, i.e., the dependence of lattice constants on the size of coherent-scattering regions. Meanwhile, no traces of oxygen nonstoichiometry and a related deviation in the effective degree of cerium oxidation from the standard value are found. The results obtained call into question the Tsunekawa model traditionally used to explain the size effect in this compound.
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Журналы
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Russian Journal of Inorganic Chemistry
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Journal of Physical Chemistry C
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Cerium Oxide (CeO₂): Synthesis, Properties and Applications
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Pleiades Publishing
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Elsevier
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Sokolov A. E. et al. On the size effect in nanocrystalline cerium dioxide: Is the Tsunekawa model correct? // Journal of Surface Investigation. 2014. Vol. 8. No. 5. pp. 997-1001.
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Sokolov A. E., Baranchikov A. E., Gil D. O., Ivanov V., Kopitsa G. P., Petrunin A. A., Fomin E. V. On the size effect in nanocrystalline cerium dioxide: Is the Tsunekawa model correct? // Journal of Surface Investigation. 2014. Vol. 8. No. 5. pp. 997-1001.
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TY - JOUR
DO - 10.1134/S1027451014050413
UR - http://link.springer.com/10.1134/S1027451014050413
TI - On the size effect in nanocrystalline cerium dioxide: Is the Tsunekawa model correct?
T2 - Journal of Surface Investigation
AU - Sokolov, A E
AU - Baranchikov, A E
AU - Gil, D O
AU - Ivanov, V.K.
AU - Kopitsa, G P
AU - Petrunin, A. A.
AU - Fomin, E V
PY - 2014
DA - 2014/09/01
PB - Pleiades Publishing
SP - 997-1001
IS - 5
VL - 8
SN - 1027-4510
SN - 1819-7094
ER -
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@article{2014_Sokolov,
author = {A E Sokolov and A E Baranchikov and D O Gil and V.K. Ivanov and G P Kopitsa and A. A. Petrunin and E V Fomin},
title = {On the size effect in nanocrystalline cerium dioxide: Is the Tsunekawa model correct?},
journal = {Journal of Surface Investigation},
year = {2014},
volume = {8},
publisher = {Pleiades Publishing},
month = {sep},
url = {http://link.springer.com/10.1134/S1027451014050413},
number = {5},
pages = {997--1001},
doi = {10.1134/S1027451014050413}
}
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Sokolov, A. E., et al. “On the size effect in nanocrystalline cerium dioxide: Is the Tsunekawa model correct?.” Journal of Surface Investigation, vol. 8, no. 5, Sep. 2014, pp. 997-1001. http://link.springer.com/10.1134/S1027451014050413.