volume 60 issue 1 pages 57-62

Crystal and molecular structure of the coordination compounds of Er3+ with 1-(methoxydiphenylphosphoryl)-2-diphenylphosphorylbenzene [ErL21 (NO3)2]2[Er(NO3)2(H2O)5]0.333(NO3)2.333 · 2.833H2O and its ethyl substituted derivative [ErL 22 (NO3)2][Er(NO3)5]0.5 · 0.5H2O

Publication typeJournal Article
Publication date2015-01-23
scimago Q4
wos Q4
SJR0.145
CiteScore0.8
Impact factor0.5
ISSN10637745, 1562689X
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
The coordination compounds of Er3+ with 1-(methoxydiphenylphosphoryl)-2-diphenylphosphorylbenzene [ErL21(NO3)2]2[Er(NO3)2(H2O)5]0.333(NO3)2.333 · 2.833H2O (I) and its ethyl substituted derivative [ErL22(NO3)2][Er(NO3)5]0.5 · 0.5H2O (II) are synthesized and their crystal structures are studied. I and II contain [ErL2(NO3)2]+ complex cations of identical composition and close structure. The eight-vertex polyhedron of the Er atom in the shape of a distorted octahedron with two split trans vertices is formed by the O atoms of the phosphoryl groups of L ligands and nitrate anions. L ligands close nine-membered metallocycles. The structures contain spacious channels which are populated differently, namely, by disordered [Er(NO3)2(H2O)5]+ complex cations, NO3− anions, and crystallization water molecules in I and disordered [Er(NO3)5]2− complex anions and crystallization water molecules in II. The IR spectra of I and II are studied.
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Polyakova I. N. et al. Crystal and molecular structure of the coordination compounds of Er3+ with 1-(methoxydiphenylphosphoryl)-2-diphenylphosphorylbenzene [ErL21 (NO3)2]2[Er(NO3)2(H2O)5]0.333(NO3)2.333 · 2.833H2O and its ethyl substituted derivative [ErL 22 (NO3)2][Er(NO3)5]0.5 · 0.5H2O // Crystallography Reports. 2015. Vol. 60. No. 1. pp. 57-62.
GOST all authors (up to 50) Copy
Polyakova I. N., Baulin V. E., Ivanova I. S., Pyatova E. N., Sergienko V. S., Tsivadze A. Y. Crystal and molecular structure of the coordination compounds of Er3+ with 1-(methoxydiphenylphosphoryl)-2-diphenylphosphorylbenzene [ErL21 (NO3)2]2[Er(NO3)2(H2O)5]0.333(NO3)2.333 · 2.833H2O and its ethyl substituted derivative [ErL 22 (NO3)2][Er(NO3)5]0.5 · 0.5H2O // Crystallography Reports. 2015. Vol. 60. No. 1. pp. 57-62.
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TY - JOUR
DO - 10.1134/S1063774515010162
UR - http://link.springer.com/10.1134/S1063774515010162
TI - Crystal and molecular structure of the coordination compounds of Er3+ with 1-(methoxydiphenylphosphoryl)-2-diphenylphosphorylbenzene [ErL21 (NO3)2]2[Er(NO3)2(H2O)5]0.333(NO3)2.333 · 2.833H2O and its ethyl substituted derivative [ErL 22 (NO3)2][Er(NO3)5]0.5 · 0.5H2O
T2 - Crystallography Reports
AU - Polyakova, I N
AU - Baulin, V E
AU - Ivanova, I. S.
AU - Pyatova, E N
AU - Sergienko, V S
AU - Tsivadze, A. Yu.
PY - 2015
DA - 2015/01/23
PB - Pleiades Publishing
SP - 57-62
IS - 1
VL - 60
SN - 1063-7745
SN - 1562-689X
ER -
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@article{2015_Polyakova,
author = {I N Polyakova and V E Baulin and I. S. Ivanova and E N Pyatova and V S Sergienko and A. Yu. Tsivadze},
title = {Crystal and molecular structure of the coordination compounds of Er3+ with 1-(methoxydiphenylphosphoryl)-2-diphenylphosphorylbenzene [ErL21 (NO3)2]2[Er(NO3)2(H2O)5]0.333(NO3)2.333 · 2.833H2O and its ethyl substituted derivative [ErL 22 (NO3)2][Er(NO3)5]0.5 · 0.5H2O},
journal = {Crystallography Reports},
year = {2015},
volume = {60},
publisher = {Pleiades Publishing},
month = {jan},
url = {http://link.springer.com/10.1134/S1063774515010162},
number = {1},
pages = {57--62},
doi = {10.1134/S1063774515010162}
}
MLA
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Polyakova, I. N., et al. “Crystal and molecular structure of the coordination compounds of Er3+ with 1-(methoxydiphenylphosphoryl)-2-diphenylphosphorylbenzene [ErL21 (NO3)2]2[Er(NO3)2(H2O)5]0.333(NO3)2.333 · 2.833H2O and its ethyl substituted derivative [ErL 22 (NO3)2][Er(NO3)5]0.5 · 0.5H2O.” Crystallography Reports, vol. 60, no. 1, Jan. 2015, pp. 57-62. http://link.springer.com/10.1134/S1063774515010162.