Submillimeter ESR spectra of Fe2+ ions in synthetic and natural beryl crystals
G S Shakurov
1
,
R I Khaibullin
1
,
V G Tomas
2
,
D A Fursenko
2
,
R. I. Mashkovtsev
2
,
O.N. Lopatin
3
,
A. G. Nikolaev
3
,
B.P. Gorshunov
4, 5
,
E S Zhukova
4, 5
1
Publication type: Journal Article
Publication date: 2017-08-24
scimago Q4
wos Q3
SJR: 0.183
CiteScore: 1.4
Impact factor: 1.8
ISSN: 10637834, 10906460, 17267498
Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Abstract
Electron spin resonance spectra of non-Kramers bivalent iron (Fe2+) ions have been detected in synthetic and natural beryl crystals with an iron impurity. The observed ESR spectra have been attributed to resonance transitions of Fe2+ ions from the ground (singlet) state to excited (doublet) levels with the splitting Δ = 12.7 cm–1 between the levels. The experimental angular and frequency dependences of the resonance field of the ESR signal have been described by the spin Hamiltonian with the effective spin S = 1. The analysis of the ESR data and optical absorption spectra indicates that the Fe2+ ions are situated in tetrahedral positions and substitute Be2+ cations in the beryl structure.
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Shakurov G. S. et al. Submillimeter ESR spectra of Fe2+ ions in synthetic and natural beryl crystals // Physics of the Solid State. 2017. Vol. 59. No. 8. pp. 1600-1606.
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Shakurov G. S., Khaibullin R. I., Tomas V. G., Fursenko D. A., Mashkovtsev R. I., Lopatin O., Nikolaev A. G., Gorshunov B., Zhukova E. S. Submillimeter ESR spectra of Fe2+ ions in synthetic and natural beryl crystals // Physics of the Solid State. 2017. Vol. 59. No. 8. pp. 1600-1606.
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TY - JOUR
DO - 10.1134/S1063783417080236
UR - https://doi.org/10.1134/S1063783417080236
TI - Submillimeter ESR spectra of Fe2+ ions in synthetic and natural beryl crystals
T2 - Physics of the Solid State
AU - Shakurov, G S
AU - Khaibullin, R I
AU - Tomas, V G
AU - Fursenko, D A
AU - Mashkovtsev, R. I.
AU - Lopatin, O.N.
AU - Nikolaev, A. G.
AU - Gorshunov, B.P.
AU - Zhukova, E S
PY - 2017
DA - 2017/08/24
PB - Pleiades Publishing
SP - 1600-1606
IS - 8
VL - 59
SN - 1063-7834
SN - 1090-6460
SN - 1726-7498
ER -
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BibTex (up to 50 authors)
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@article{2017_Shakurov,
author = {G S Shakurov and R I Khaibullin and V G Tomas and D A Fursenko and R. I. Mashkovtsev and O.N. Lopatin and A. G. Nikolaev and B.P. Gorshunov and E S Zhukova},
title = {Submillimeter ESR spectra of Fe2+ ions in synthetic and natural beryl crystals},
journal = {Physics of the Solid State},
year = {2017},
volume = {59},
publisher = {Pleiades Publishing},
month = {aug},
url = {https://doi.org/10.1134/S1063783417080236},
number = {8},
pages = {1600--1606},
doi = {10.1134/S1063783417080236}
}
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MLA
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Shakurov, G. S., et al. “Submillimeter ESR spectra of Fe2+ ions in synthetic and natural beryl crystals.” Physics of the Solid State, vol. 59, no. 8, Aug. 2017, pp. 1600-1606. https://doi.org/10.1134/S1063783417080236.