volume 59 issue 8 pages 1600-1606

Submillimeter ESR spectra of Fe2+ ions in synthetic and natural beryl crystals

G S Shakurov 1
R I Khaibullin 1
V G Tomas 2
D A Fursenko 2
R. I. Mashkovtsev 2
O.N. Lopatin 3
A. G. Nikolaev 3
B.P. Gorshunov 4, 5
Publication typeJournal Article
Publication date2017-08-24
scimago Q4
wos Q3
SJR0.183
CiteScore1.4
Impact factor1.8
ISSN10637834, 10906460, 17267498
Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Abstract
Electron spin resonance spectra of non-Kramers bivalent iron (Fe2+) ions have been detected in synthetic and natural beryl crystals with an iron impurity. The observed ESR spectra have been attributed to resonance transitions of Fe2+ ions from the ground (singlet) state to excited (doublet) levels with the splitting Δ = 12.7 cm–1 between the levels. The experimental angular and frequency dependences of the resonance field of the ESR signal have been described by the spin Hamiltonian with the effective spin S = 1. The analysis of the ESR data and optical absorption spectra indicates that the Fe2+ ions are situated in tetrahedral positions and substitute Be2+ cations in the beryl structure.
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Shakurov G. S. et al. Submillimeter ESR spectra of Fe2+ ions in synthetic and natural beryl crystals // Physics of the Solid State. 2017. Vol. 59. No. 8. pp. 1600-1606.
GOST all authors (up to 50) Copy
Shakurov G. S., Khaibullin R. I., Tomas V. G., Fursenko D. A., Mashkovtsev R. I., Lopatin O., Nikolaev A. G., Gorshunov B., Zhukova E. S. Submillimeter ESR spectra of Fe2+ ions in synthetic and natural beryl crystals // Physics of the Solid State. 2017. Vol. 59. No. 8. pp. 1600-1606.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S1063783417080236
UR - https://doi.org/10.1134/S1063783417080236
TI - Submillimeter ESR spectra of Fe2+ ions in synthetic and natural beryl crystals
T2 - Physics of the Solid State
AU - Shakurov, G S
AU - Khaibullin, R I
AU - Tomas, V G
AU - Fursenko, D A
AU - Mashkovtsev, R. I.
AU - Lopatin, O.N.
AU - Nikolaev, A. G.
AU - Gorshunov, B.P.
AU - Zhukova, E S
PY - 2017
DA - 2017/08/24
PB - Pleiades Publishing
SP - 1600-1606
IS - 8
VL - 59
SN - 1063-7834
SN - 1090-6460
SN - 1726-7498
ER -
BibTex |
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@article{2017_Shakurov,
author = {G S Shakurov and R I Khaibullin and V G Tomas and D A Fursenko and R. I. Mashkovtsev and O.N. Lopatin and A. G. Nikolaev and B.P. Gorshunov and E S Zhukova},
title = {Submillimeter ESR spectra of Fe2+ ions in synthetic and natural beryl crystals},
journal = {Physics of the Solid State},
year = {2017},
volume = {59},
publisher = {Pleiades Publishing},
month = {aug},
url = {https://doi.org/10.1134/S1063783417080236},
number = {8},
pages = {1600--1606},
doi = {10.1134/S1063783417080236}
}
MLA
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MLA Copy
Shakurov, G. S., et al. “Submillimeter ESR spectra of Fe2+ ions in synthetic and natural beryl crystals.” Physics of the Solid State, vol. 59, no. 8, Aug. 2017, pp. 1600-1606. https://doi.org/10.1134/S1063783417080236.