Radiochemistry

, том 57 , издание 1 , страницы 61-68

Acidic phosphoryl podands as components of impregnation-type sorbents for ⁹⁹Mo recovery from nitric acid solutions

Тип публикации: Journal Article

Дата публикации: 2015-01-01

Pleiades Publishing

Radiochemistry

scimago Q3

wos Q4

БС3

SJR: 0.285

CiteScore: 1.6

Impact factor: 1.0

ISSN: 10663622, 16083288

DOI: 10.1134/S1066362215010099

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Physical and Theoretical Chemistry

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A series of phosphoryl podands of acid type, differing in the length of the polyether chain and structure of the terminal group, were synthesized. The compounds obtained were tested as complexing components of impregnation-type sorbents. The regular trends of the Mo sorption from model solutions of ammonium molybdate in HNO3 in relation to the qualitative and quantitative composition of the sorbents were studied by extraction chromatography. The composition of a new impregnation-type complexing sorbent for selective recovery of Mo from nitric acid solutions was developed and optimized, and conditions were determined for its practical use. The sorbent allows efficient recovery of 99Mo and its separation from products of reprocessing of irradiated uranium materials in process solutions of the Mayak Production Association. The sorbent also allows separation of 99Mo and 99mTc, which makes it potentially suitable for use in 99Mo/99mTc generators of chromatographic type.

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Бежин Николай

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к.х.н., доц.

37 публикаций, 272 цитирования, 59 рецензий

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Севастопольский государственный университет

Сахалинский государственный университет

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Russian Journal of Inorganic Chemistry	Russian Journal of Inorganic Chemistry, 5, 50% Russian Journal of Inorganic Chemistry 5 публикаций, 50%
Solvent Extraction and Ion Exchange	Solvent Extraction and Ion Exchange, 1, 10% Solvent Extraction and Ion Exchange 1 публикация, 10%
Protection of Metals and Physical Chemistry of Surfaces	Protection of Metals and Physical Chemistry of Surfaces, 1, 10% Protection of Metals and Physical Chemistry of Surfaces 1 публикация, 10%
Journal of Radioanalytical and Nuclear Chemistry	Journal of Radioanalytical and Nuclear Chemistry, 1, 10% Journal of Radioanalytical and Nuclear Chemistry 1 публикация, 10%
Microchemical Journal	Microchemical Journal, 1, 10% Microchemical Journal 1 публикация, 10%
Biomedical Chemistry Research and Methods	Biomedical Chemistry Research and Methods, 1, 10% Biomedical Chemistry Research and Methods 1 публикация, 10%
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Pleiades Publishing	Pleiades Publishing, 6, 60% Pleiades Publishing 6 публикаций, 60%
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Institute of Biomedical Chemistry	Institute of Biomedical Chemistry, 1, 10% Institute of Biomedical Chemistry 1 публикация, 10%
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Baulin V. E. et al. Acidic phosphoryl podands as components of impregnation-type sorbents for 99Mo recovery from nitric acid solutions // Radiochemistry. 2015. Vol. 57. No. 1. pp. 61-68.

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Baulin V. E., Kovalenko O. V., Turanov A., Karandashev V. K., Usolkin A. N., Yakovlev N. G., Voroshilov Yu. A., Tsivadze A. Y. Acidic phosphoryl podands as components of impregnation-type sorbents for 99Mo recovery from nitric acid solutions // Radiochemistry. 2015. Vol. 57. No. 1. pp. 61-68.

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TY - JOUR

DO - 10.1134/S1066362215010099

UR - http://link.springer.com/10.1134/S1066362215010099

TI - Acidic phosphoryl podands as components of impregnation-type sorbents for 99Mo recovery from nitric acid solutions

T2 - Radiochemistry

AU - Baulin, V E

AU - Kovalenko, O. V.

AU - Turanov, A.N.

AU - Karandashev, V K

AU - Usolkin, A N

AU - Yakovlev, N G

AU - Voroshilov, Yu A

AU - Tsivadze, A. Yu.

PY - 2015

DA - 2015/01/01

PB - Pleiades Publishing

SP - 61-68

IS - 1

VL - 57

SN - 1066-3622

SN - 1608-3288

ER -

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@article{2015_Baulin,

author = {V E Baulin and O. V. Kovalenko and A.N. Turanov and V K Karandashev and A N Usolkin and N G Yakovlev and Yu A Voroshilov and A. Yu. Tsivadze},

title = {Acidic phosphoryl podands as components of impregnation-type sorbents for 99Mo recovery from nitric acid solutions},

journal = {Radiochemistry},

year = {2015},

volume = {57},

publisher = {Pleiades Publishing},

month = {jan},

url = {http://link.springer.com/10.1134/S1066362215010099},

number = {1},

pages = {61--68},

doi = {10.1134/S1066362215010099}

}

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Baulin, V. E., et al. “Acidic phosphoryl podands as components of impregnation-type sorbents for 99Mo recovery from nitric acid solutions.” Radiochemistry, vol. 57, no. 1, Jan. 2015, pp. 61-68. http://link.springer.com/10.1134/S1066362215010099.