Lithium 1,5-bis[2-dioxyphosphinyl)phenoxy]-3-oxapentane hydrate: Synthesis, vibrational spectra, and crystal structure

Publication type: Journal Article
Publication date: 2011-06-17
Pleiades Publishing
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The complex [Li(H3L2)(H2O)]n (I), where H4L2 is 1,5-bis[2-(dioxyphosphinyl)phenoxy]-3-oxapentane, is synthesized. Its crystal and molecular structures are determined by X-ray diffraction analysis and vibrational spectroscopy. Complex I is an isolated chain polymer in which the Li+ cations bind anions (H3L2)− of the bridging ligand. The crystals are orthorhombic: a = 8.1860(3) Å, b = 9.9093(4) Å, c = 23.6293(8) Å, V = 1916.75(12) Å3, Z = 4, space group Pna21. The framework of the polymer chain is stabilized by hydrogen bonds between two hydrogen atoms of the coordinated water molecule and two oxygen atoms of the ether and phosphone groups.
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Baulin V. E. et al. Lithium 1,5-bis[2-dioxyphosphinyl)phenoxy]-3-oxapentane hydrate: Synthesis, vibrational spectra, and crystal structure // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2011. Vol. 37. No. 6. pp. 405-410.
GOST all authors (up to 50) Copy
Baulin V. E., Kiskin M. A., Ivanova I. S., Pyatova E. N., Baulin D. V., Tsivadze A. Y. Lithium 1,5-bis[2-dioxyphosphinyl)phenoxy]-3-oxapentane hydrate: Synthesis, vibrational spectra, and crystal structure // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2011. Vol. 37. No. 6. pp. 405-410.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S1070328411050010
UR - http://link.springer.com/10.1134/S1070328411050010
TI - Lithium 1,5-bis[2-dioxyphosphinyl)phenoxy]-3-oxapentane hydrate: Synthesis, vibrational spectra, and crystal structure
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Baulin, V E
AU - Kiskin, M. A.
AU - Ivanova, I. S.
AU - Pyatova, E N
AU - Baulin, D V
AU - Tsivadze, A. Yu.
PY - 2011
DA - 2011/06/17
PB - Pleiades Publishing
SP - 405-410
IS - 6
VL - 37
SN - 1070-3284
SN - 1608-3318
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2011_Baulin,
author = {V E Baulin and M. A. Kiskin and I. S. Ivanova and E N Pyatova and D V Baulin and A. Yu. Tsivadze},
title = {Lithium 1,5-bis[2-dioxyphosphinyl)phenoxy]-3-oxapentane hydrate: Synthesis, vibrational spectra, and crystal structure},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2011},
volume = {37},
publisher = {Pleiades Publishing},
month = {jun},
url = {http://link.springer.com/10.1134/S1070328411050010},
number = {6},
pages = {405--410},
doi = {10.1134/S1070328411050010}
}
MLA
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MLA Copy
Baulin, V. E., et al. “Lithium 1,5-bis[2-dioxyphosphinyl)phenoxy]-3-oxapentane hydrate: Synthesis, vibrational spectra, and crystal structure.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 37, no. 6, Jun. 2011, pp. 405-410. http://link.springer.com/10.1134/S1070328411050010.