,
volume 37
,
issue 8
,
pages 625-634
Binary palladium carboxylates with electron-donating and electron-withdrawing substituents in the carboxylate ligand: Synthesis and structural studies. the crystal structures of Pd3 (μ-CH 2 ClCO2 )6 • CH2 Cl2 , Pd3 (μ-C6 H11 CO2 )6 , and Pd3
I A Efimenko
1
,
R E Podobedov
1, 2
,
A.V. Churakov
1
,
L. G. Kuz'mina
1
,
I A Garbuzova
3
,
B V Lokshin
3
,
A L Maksimov
4
,
V R Flid
2
1
Publication type: Journal Article
Publication date: 2011-08-04
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
Replacement of the acetate ligands in Pd3(μ-MeCO2)6 in benzene gave complexes of the general formula Pd3(μ-RCO2)6 (R = CF3, CCl3, CH2Cl, Me, cyclo-C6H11, and CMe3). The structures of the complexes were determined using IR spectroscopy, ESI mass spectrometry, and X-ray diffraction. It was found that the complexes contain a trinuclear Pd framework and that their spectroscopic and structural parameters depend on the donor-acceptor properties of the substituent in the carboxylate ligand.
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Citations from 2024:
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Efimenko I. A. et al. Binary palladium carboxylates with electron-donating and electron-withdrawing substituents in the carboxylate ligand: Synthesis and structural studies. the crystal structures of Pd3(μ-CH 2ClCO2)6 • CH2Cl2, Pd3(μ-C6H11CO2)6, and Pd3 // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2011. Vol. 37. No. 8. pp. 625-634.
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Efimenko I. A., Podobedov R. E., Churakov A., Kuz'mina L. G., Garbuzova I. A., Lokshin B. V., Maksimov A. L., Flid V. R. Binary palladium carboxylates with electron-donating and electron-withdrawing substituents in the carboxylate ligand: Synthesis and structural studies. the crystal structures of Pd3(μ-CH 2ClCO2)6 • CH2Cl2, Pd3(μ-C6H11CO2)6, and Pd3 // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2011. Vol. 37. No. 8. pp. 625-634.
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TY - JOUR
DO - 10.1134/S1070328411080021
UR - http://link.springer.com/10.1134/S1070328411080021
TI - Binary palladium carboxylates with electron-donating and electron-withdrawing substituents in the carboxylate ligand: Synthesis and structural studies. the crystal structures of Pd3(μ-CH 2ClCO2)6 • CH2Cl2, Pd3(μ-C6H11CO2)6, and Pd3
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Efimenko, I A
AU - Podobedov, R E
AU - Churakov, A.V.
AU - Kuz'mina, L. G.
AU - Garbuzova, I A
AU - Lokshin, B V
AU - Maksimov, A L
AU - Flid, V R
PY - 2011
DA - 2011/08/04
PB - Pleiades Publishing
SP - 625-634
IS - 8
VL - 37
SN - 1070-3284
SN - 1608-3318
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2011_Efimenko,
author = {I A Efimenko and R E Podobedov and A.V. Churakov and L. G. Kuz'mina and I A Garbuzova and B V Lokshin and A L Maksimov and V R Flid},
title = {Binary palladium carboxylates with electron-donating and electron-withdrawing substituents in the carboxylate ligand: Synthesis and structural studies. the crystal structures of Pd3(μ-CH 2ClCO2)6 • CH2Cl2, Pd3(μ-C6H11CO2)6, and Pd3},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2011},
volume = {37},
publisher = {Pleiades Publishing},
month = {aug},
url = {http://link.springer.com/10.1134/S1070328411080021},
number = {8},
pages = {625--634},
doi = {10.1134/S1070328411080021}
}
Cite this
MLA
Copy
Efimenko, I. A., et al. “Binary palladium carboxylates with electron-donating and electron-withdrawing substituents in the carboxylate ligand: Synthesis and structural studies. the crystal structures of Pd3(μ-CH 2ClCO2)6 • CH2Cl2, Pd3(μ-C6H11CO2)6, and Pd3.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 37, no. 8, Aug. 2011, pp. 625-634. http://link.springer.com/10.1134/S1070328411080021.