,
volume 41
,
issue 12
,
pages 777-786
Syntheses and structures of heterometallic complexes M-Co(II) (M = Li(I), Mg(II), and Eu(III)) with anions of 2-naphthoic acid. An influence of the heterometal on the structure of the complex
Publication type: Journal Article
Publication date: 2015-11-22
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
A series of polynuclear heterometallic cobalt(II) 2-naphthoate complexes with lithium(I), magnesium(II), and europium(III) is synthesized: [(2,2′-Bipy)2Li2Co2(Naph)6], [(2,4-Lut)2Co2Mg(Naph)6], and [(2,2′-Bipy)2(EtOH)2Co2Eu2(Naph)10] (Naph is 2-naphthoic acid anion, 2,2′-Bipy is 2,2′-bipyridine, and 2,4-Lut is 2,4-lutidine). The single crystals of the synthesized compounds are characterized by X-ray diffraction analysis (CIF files CCDC 1401987 (I), 1401988 (II), 1401989 (III), and 1401990 (IV)). The compositions and structures of the molecular heterometallic complexes based on cobalt(II) cations and anions of 2-naphthoic acid are determined by the radius and coordination number of the introduced heterometal: the isomorphic substitution of one of the cobalt(II) ions is observed for the magnesium(II) complex, and tetranuclear complexes are formed in the case of lithium(I) and europium(III).
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Goldberg A. E. et al. Syntheses and structures of heterometallic complexes M-Co(II) (M = Li(I), Mg(II), and Eu(III)) with anions of 2-naphthoic acid. An influence of the heterometal on the structure of the complex // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2015. Vol. 41. No. 12. pp. 777-786.
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Goldberg A. E., Nikolaevskii S. A., Kiskin M. A., Sidorov A. A., Eremenko I. L. Syntheses and structures of heterometallic complexes M-Co(II) (M = Li(I), Mg(II), and Eu(III)) with anions of 2-naphthoic acid. An influence of the heterometal on the structure of the complex // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2015. Vol. 41. No. 12. pp. 777-786.
Cite this
RIS
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TY - JOUR
DO - 10.1134/S1070328415120015
UR - https://doi.org/10.1134/S1070328415120015
TI - Syntheses and structures of heterometallic complexes M-Co(II) (M = Li(I), Mg(II), and Eu(III)) with anions of 2-naphthoic acid. An influence of the heterometal on the structure of the complex
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Goldberg, A E
AU - Nikolaevskii, S A
AU - Kiskin, M. A.
AU - Sidorov, A. A.
AU - Eremenko, I. L.
PY - 2015
DA - 2015/11/22
PB - Pleiades Publishing
SP - 777-786
IS - 12
VL - 41
SN - 1070-3284
SN - 1608-3318
ER -
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BibTex (up to 50 authors)
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@article{2015_Goldberg,
author = {A E Goldberg and S A Nikolaevskii and M. A. Kiskin and A. A. Sidorov and I. L. Eremenko},
title = {Syntheses and structures of heterometallic complexes M-Co(II) (M = Li(I), Mg(II), and Eu(III)) with anions of 2-naphthoic acid. An influence of the heterometal on the structure of the complex},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2015},
volume = {41},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134/S1070328415120015},
number = {12},
pages = {777--786},
doi = {10.1134/S1070328415120015}
}
Cite this
MLA
Copy
Goldberg, A. E., et al. “Syntheses and structures of heterometallic complexes M-Co(II) (M = Li(I), Mg(II), and Eu(III)) with anions of 2-naphthoic acid. An influence of the heterometal on the structure of the complex.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 41, no. 12, Nov. 2015, pp. 777-786. https://doi.org/10.1134/S1070328415120015.