,
volume 43
,
issue 6
,
pages 345-351
New approach to the synthesis of polynuclear heterometallic pivalates with iron and manganese atoms
Publication type: Journal Article
Publication date: 2017-06-10
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
New hexanuclear Fe(III)–Mn(II, III) pivalates [Fe2III Mn4II(O)2(Piv)10(HPiv)4] (I) or [Fe4III Mn2III(O)2(Piv)12(CH2O2)(HPiv)2] · Et2O (II) are synthesized using the solid-state thermolysis of [Fe2Mn(O)(Piv)6(HPiv)3] (90°С). Complexes I and II differ by the ratio of iron and manganese ions, which depends on the atmospheric composition during thermolysis. The structures of compounds I and II are determined by X-ray diffraction studies. According to the parameters of the Mössbauer spectrum, complex I contains the Fe3+ ions in the high-spin state in the octahedral environment of oxygen atoms.
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Lutsenko I. A. et al. New approach to the synthesis of polynuclear heterometallic pivalates with iron and manganese atoms // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017. Vol. 43. No. 6. pp. 345-351.
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Lutsenko I. A., Kiskin M. A., Imshennik V., Maksimov Y. V., Sidorov A. A., Eremenko I. L. New approach to the synthesis of polynuclear heterometallic pivalates with iron and manganese atoms // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017. Vol. 43. No. 6. pp. 345-351.
Cite this
RIS
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TY - JOUR
DO - 10.1134/S1070328417060033
UR - https://doi.org/10.1134/S1070328417060033
TI - New approach to the synthesis of polynuclear heterometallic pivalates with iron and manganese atoms
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Lutsenko, I A
AU - Kiskin, M. A.
AU - Imshennik, V.K
AU - Maksimov, Yu. V.
AU - Sidorov, A. A.
AU - Eremenko, I. L.
PY - 2017
DA - 2017/06/10
PB - Pleiades Publishing
SP - 345-351
IS - 6
VL - 43
SN - 1070-3284
SN - 1608-3318
ER -
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BibTex (up to 50 authors)
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@article{2017_Lutsenko,
author = {I A Lutsenko and M. A. Kiskin and V.K Imshennik and Yu. V. Maksimov and A. A. Sidorov and I. L. Eremenko},
title = {New approach to the synthesis of polynuclear heterometallic pivalates with iron and manganese atoms},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2017},
volume = {43},
publisher = {Pleiades Publishing},
month = {jun},
url = {https://doi.org/10.1134/S1070328417060033},
number = {6},
pages = {345--351},
doi = {10.1134/S1070328417060033}
}
Cite this
MLA
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Lutsenko, I. A., et al. “New approach to the synthesis of polynuclear heterometallic pivalates with iron and manganese atoms.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 43, no. 6, Jun. 2017, pp. 345-351. https://doi.org/10.1134/S1070328417060033.