volume 43 issue 11 pages 709-717

Examples of cation exchange in new ionic oxovanadium(IV) complexes with anions of cyclobutane-1,1-dicarboxylic acid

Publication typeJournal Article
Publication date2017-11-13
scimago Q4
wos Q4
SJR0.189
CiteScore1.7
Impact factor1.1
ISSN10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The results on the synthesis and study of the crystal structures of compounds based on anionic fragments {VO(Cbdc)2}2– formed by oxovanadium(IV) (vanadyl, VO2+) and two chelate-bound anions of cyclobutane-1,1-dicarboxylic acid (H2Cbdc = C4H6(COOH)2) are presented. The use of ammonium cation NH4+ as a counterion in the synthesis leads to the formation of the mononuclear complex (NH4)2[VO(Сbdc)2(H2O)] · 2H2O (I). In the case of K+ cation, compound [K4(VO)2(Сbdc)4(H2O)4]n (II) with the 3D polymeric crystal structure is formed. The reaction of compound II with Mg(NO3)2 · 6H2O in an aqueous solution involves the partial substitution of K+ by Mg2+ cations to form 1D polymeric compound {[KMg0.5(VO)(Сbdc)2(H2O)6.5] · 3H2O}n (III), while a similar reaction of compound I does not afford the product of substitution of NH4+ by Mg2+ cations (CIF files CCDC 1551021–1551023 for compounds I–III, respectively).
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Bazhina E. S. et al. Examples of cation exchange in new ionic oxovanadium(IV) complexes with anions of cyclobutane-1,1-dicarboxylic acid // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017. Vol. 43. No. 11. pp. 709-717.
GOST all authors (up to 50) Copy
Bazhina E. S., Aleksandrov G., Kiskin M. A., Sidorov A. A., Eremenko I. L. Examples of cation exchange in new ionic oxovanadium(IV) complexes with anions of cyclobutane-1,1-dicarboxylic acid // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017. Vol. 43. No. 11. pp. 709-717.
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TY - JOUR
DO - 10.1134/S107032841711001X
UR - https://doi.org/10.1134/S107032841711001X
TI - Examples of cation exchange in new ionic oxovanadium(IV) complexes with anions of cyclobutane-1,1-dicarboxylic acid
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Bazhina, E S
AU - Aleksandrov, G.G.
AU - Kiskin, M. A.
AU - Sidorov, A. A.
AU - Eremenko, I. L.
PY - 2017
DA - 2017/11/13
PB - Pleiades Publishing
SP - 709-717
IS - 11
VL - 43
SN - 1070-3284
SN - 1608-3318
ER -
BibTex |
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@article{2017_Bazhina,
author = {E S Bazhina and G.G. Aleksandrov and M. A. Kiskin and A. A. Sidorov and I. L. Eremenko},
title = {Examples of cation exchange in new ionic oxovanadium(IV) complexes with anions of cyclobutane-1,1-dicarboxylic acid},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2017},
volume = {43},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134/S107032841711001X},
number = {11},
pages = {709--717},
doi = {10.1134/S107032841711001X}
}
MLA
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Bazhina, E. S., et al. “Examples of cation exchange in new ionic oxovanadium(IV) complexes with anions of cyclobutane-1,1-dicarboxylic acid.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 43, no. 11, Nov. 2017, pp. 709-717. https://doi.org/10.1134/S107032841711001X.