,
volume 43
,
issue 12
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pages 843-851
New catecholate complexes of triphenylantimony(V) based on 6-iminomethyl-3,5-di-tert-butylpyrocatechols N-functionalized by the aniline or phenol group
Publication type: Journal Article
Publication date: 2017-12-07
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The following new triphenylantimony(V) catecholate complexes bearing the protonated imine group are synthesized from the new sterically hindered 3,5-di-tert-butylpyrocatechols (6-(CH=N-o-(C6H4–NH2))-3,5-Cat)H2 (H2L1) and (6-(CH=N-o-(C6H4–OH))-3,5-Cat)H2 (H2L2) containing in position 6 the iminomethyl group bonded to the aniline or phenol substituent: (6-(CH=NH+-o-(C6H4–NH2))-3,5-Cat)SbPh3X (X = Br (I), OMe (III)) and (6-(CH=NH+-o-(C6H4–OH))-3,5-Cat)SbPh3X (X = Br (II), OMe (IV)). The molecular structure of complex III · CH 3 OH in the crystalline state is determined by X-ray diffraction analysis (CIF file CCDC no. 1554694). The electrochemical properties of complexes III and IV are studied by cyclic voltammetry.
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Poddelsky A. I. et al. New catecholate complexes of triphenylantimony(V) based on 6-iminomethyl-3,5-di-tert-butylpyrocatechols N-functionalized by the aniline or phenol group // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017. Vol. 43. No. 12. pp. 843-851.
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Poddelsky A. I., Arsenev M. V., Okhlopkova L. S., Smolyaninov I. V., Fukin G. K. New catecholate complexes of triphenylantimony(V) based on 6-iminomethyl-3,5-di-tert-butylpyrocatechols N-functionalized by the aniline or phenol group // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017. Vol. 43. No. 12. pp. 843-851.
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RIS
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TY - JOUR
DO - 10.1134/S1070328417120089
UR - https://doi.org/10.1134/S1070328417120089
TI - New catecholate complexes of triphenylantimony(V) based on 6-iminomethyl-3,5-di-tert-butylpyrocatechols N-functionalized by the aniline or phenol group
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Poddelsky, A I
AU - Arsenev, M V
AU - Okhlopkova, L S
AU - Smolyaninov, I V
AU - Fukin, G. K.
PY - 2017
DA - 2017/12/07
PB - Pleiades Publishing
SP - 843-851
IS - 12
VL - 43
SN - 1070-3284
SN - 1608-3318
ER -
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BibTex (up to 50 authors)
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@article{2017_Poddelsky,
author = {A I Poddelsky and M V Arsenev and L S Okhlopkova and I V Smolyaninov and G. K. Fukin},
title = {New catecholate complexes of triphenylantimony(V) based on 6-iminomethyl-3,5-di-tert-butylpyrocatechols N-functionalized by the aniline or phenol group},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2017},
volume = {43},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1134/S1070328417120089},
number = {12},
pages = {843--851},
doi = {10.1134/S1070328417120089}
}
Cite this
MLA
Copy
Poddelsky, A. I., et al. “New catecholate complexes of triphenylantimony(V) based on 6-iminomethyl-3,5-di-tert-butylpyrocatechols N-functionalized by the aniline or phenol group.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 43, no. 12, Dec. 2017, pp. 843-851. https://doi.org/10.1134/S1070328417120089.