,
volume 44
,
issue 11
,
pages 647-652
Chalcogenide Complexes of Cyclopentadienylnickel with Heterocyclic Carbene
S S Shapovalov
1
,
A A Pasynskii
1
,
I V Skabitskii
1
,
O G Tikhonova
1
,
A V Kolos
1
,
M O Grigoreva
1
Publication type: Journal Article
Publication date: 2018-10-12
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The monomeric complex (η5-C5H5)Ni(Me2Im)SnPr synthesized by the reaction of the [(η5‑C5H5)Ni(μ-SnPr)]2 dimer with dimethylimidazolium carboxylate is rapidly oxidized in air to form the sulfone complex (η5-C5H5)Ni(Me2Im)S(O)2nPr (I), while its reaction with the adduct W(CO)5(ТHF) affords (η5-C5H5)Ni(Me2Im)(μ-SnPr)W(CO)5 (II). A new heterometallic complex (η5‑C5H5)Ni(Me2Im)TeI2Fc (III) containing the terminal telluroferrocenyl fragment is obtained by the reaction of the known nickel carbene complex (η5-C5H5)Ni(Me2Im)I with FcTeI (Fc = (η5-C5H4)Fe(η5-C5H5)). The complexes synthesized are studied by X-ray structure analysis (CIF files CCDC nos. 1835574, 1835573, and 1835572 for compounds I, II, and III, respectively).
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Shapovalov S. S. et al. Chalcogenide Complexes of Cyclopentadienylnickel with Heterocyclic Carbene // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2018. Vol. 44. No. 11. pp. 647-652.
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Shapovalov S. S., Pasynskii A. A., Skabitskii I. V., Tikhonova O. G., Kolos A. V., Grigoreva M. O. Chalcogenide Complexes of Cyclopentadienylnickel with Heterocyclic Carbene // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2018. Vol. 44. No. 11. pp. 647-652.
Cite this
RIS
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TY - JOUR
DO - 10.1134/S1070328418110076
UR - https://doi.org/10.1134/S1070328418110076
TI - Chalcogenide Complexes of Cyclopentadienylnickel with Heterocyclic Carbene
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Shapovalov, S S
AU - Pasynskii, A A
AU - Skabitskii, I V
AU - Tikhonova, O G
AU - Kolos, A V
AU - Grigoreva, M O
PY - 2018
DA - 2018/10/12
PB - Pleiades Publishing
SP - 647-652
IS - 11
VL - 44
SN - 1070-3284
SN - 1608-3318
ER -
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BibTex (up to 50 authors)
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@article{2018_Shapovalov,
author = {S S Shapovalov and A A Pasynskii and I V Skabitskii and O G Tikhonova and A V Kolos and M O Grigoreva},
title = {Chalcogenide Complexes of Cyclopentadienylnickel with Heterocyclic Carbene},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2018},
volume = {44},
publisher = {Pleiades Publishing},
month = {oct},
url = {https://doi.org/10.1134/S1070328418110076},
number = {11},
pages = {647--652},
doi = {10.1134/S1070328418110076}
}
Cite this
MLA
Copy
Shapovalov, S. S., et al. “Chalcogenide Complexes of Cyclopentadienylnickel with Heterocyclic Carbene.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 44, no. 11, Oct. 2018, pp. 647-652. https://doi.org/10.1134/S1070328418110076.