,
volume 44
,
issue 12
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pages 745-754
Peculiarities of the Interaction of Rare-Earth Metal Thiocyanates with s-Triazine
Publication type: Journal Article
Publication date: 2018-12-01
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The reactions of thiocyanates Ln(NCS)3 ⋅ 6H2O (Ln = Y, Eu, and Tb) with 2,4,6-tris(2-pyridyl)-s-triazine (Tptz) in МеОН, MeCN, and H2O afford neutral or ionic thiocyanate complexes with one coordinated Tptz molecule. The uniqueness of the complexes is the presence of the second Tptz molecule in the exo coordination. The transformation of Tptz into the endo coordination occurs upon recrystallization from an aprotic solvent. The structural peculiarities of the synthesized compounds are determined by powder X-ray diffraction, IR spectroscopy, and single-crystal X-ray diffraction (CIF files CCDC nos. 1827916–1827921).
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Petrosyants S. P. et al. Peculiarities of the Interaction of Rare-Earth Metal Thiocyanates with s-Triazine // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2018. Vol. 44. No. 12. pp. 745-754.
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Petrosyants S. P., Ilyukhin A. B., Gavrikov A. V., Efimov N. N. Peculiarities of the Interaction of Rare-Earth Metal Thiocyanates with s-Triazine // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2018. Vol. 44. No. 12. pp. 745-754.
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TY - JOUR
DO - 10.1134/S1070328418120060
UR - http://link.springer.com/10.1134/S1070328418120060
TI - Peculiarities of the Interaction of Rare-Earth Metal Thiocyanates with s-Triazine
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Petrosyants, S P
AU - Ilyukhin, A. B.
AU - Gavrikov, A. V.
AU - Efimov, N. N.
PY - 2018
DA - 2018/12/01
PB - Pleiades Publishing
SP - 745-754
IS - 12
VL - 44
SN - 1070-3284
SN - 1608-3318
ER -
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BibTex (up to 50 authors)
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@article{2018_Petrosyants,
author = {S P Petrosyants and A. B. Ilyukhin and A. V. Gavrikov and N. N. Efimov},
title = {Peculiarities of the Interaction of Rare-Earth Metal Thiocyanates with s-Triazine},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2018},
volume = {44},
publisher = {Pleiades Publishing},
month = {dec},
url = {http://link.springer.com/10.1134/S1070328418120060},
number = {12},
pages = {745--754},
doi = {10.1134/S1070328418120060}
}
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MLA
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Petrosyants, S. P., et al. “Peculiarities of the Interaction of Rare-Earth Metal Thiocyanates with s-Triazine.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 44, no. 12, Dec. 2018, pp. 745-754. http://link.springer.com/10.1134/S1070328418120060.
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