,
volume 46
,
issue 4
,
pages 260-267
Molecular Structure and Photoluminescence Behavior of the Zn(II) Carboxylate Complex with Pyrazino[2,3-f][1,10]phenanthroline
Publication type: Journal Article
Publication date: 2020-04-10
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
Abstract A new complex [Zn(Piv) 2 (Pyzphen)] ( I ) was prepared by the reaction of pyrazino[2,3-f][1,10]phenanthroline (Pyzphen) with Zn(II) pivalate [Zn(Piv) 2 ] n . An X-ray diffraction study (CIF file CCDC no. 1912821) revealed that complex I has a mononuclear structure, with ZnN 2 O 4 coordination unit being a distorted trigonal prism. Quantum chemical simulation of dimerization of complex I , resulting in the hypothetical binuclear product [Zn(Piv) 2 (Pyzphen)] 2 ( II ), showed that two energy demanding transition states present on the path of association of the complex molecules may prevent the experimental isolation of binuclear complex II . According to the results of luminescence studies of the Pyzphen ligand and complex I , the ligand emission band shifts to the blue region upon coordination to zinc(II) ion.
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Nikolaevskii S. A. et al. Molecular Structure and Photoluminescence Behavior of the Zn(II) Carboxylate Complex with Pyrazino[2,3-f][1,10]phenanthroline // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2020. Vol. 46. No. 4. pp. 260-267.
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Nikolaevskii S. A., Yambulatov D. S., Starikova A. A., Sidorov A. A., Kiskin M. A., Eremenko I. L. Molecular Structure and Photoluminescence Behavior of the Zn(II) Carboxylate Complex with Pyrazino[2,3-f][1,10]phenanthroline // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2020. Vol. 46. No. 4. pp. 260-267.
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RIS
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TY - JOUR
DO - 10.1134/S1070328420040053
UR - https://doi.org/10.1134/S1070328420040053
TI - Molecular Structure and Photoluminescence Behavior of the Zn(II) Carboxylate Complex with Pyrazino[2,3-f][1,10]phenanthroline
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Nikolaevskii, S A
AU - Yambulatov, D S
AU - Starikova, A A
AU - Sidorov, A. A.
AU - Kiskin, M. A.
AU - Eremenko, I. L.
PY - 2020
DA - 2020/04/10
PB - Pleiades Publishing
SP - 260-267
IS - 4
VL - 46
SN - 1070-3284
SN - 1608-3318
ER -
Cite this
BibTex (up to 50 authors)
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@article{2020_Nikolaevskii,
author = {S A Nikolaevskii and D S Yambulatov and A A Starikova and A. A. Sidorov and M. A. Kiskin and I. L. Eremenko},
title = {Molecular Structure and Photoluminescence Behavior of the Zn(II) Carboxylate Complex with Pyrazino[2,3-f][1,10]phenanthroline},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2020},
volume = {46},
publisher = {Pleiades Publishing},
month = {apr},
url = {https://doi.org/10.1134/S1070328420040053},
number = {4},
pages = {260--267},
doi = {10.1134/S1070328420040053}
}
Cite this
MLA
Copy
Nikolaevskii, S. A., et al. “Molecular Structure and Photoluminescence Behavior of the Zn(II) Carboxylate Complex with Pyrazino[2,3-f][1,10]phenanthroline.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 46, no. 4, Apr. 2020, pp. 260-267. https://doi.org/10.1134/S1070328420040053.