,
volume 46
,
issue 11
,
pages 772-778
Copper(II) Trimethylacetate Complex with Caffeine: Synthesis, Structure, and Biological Activity
D S Yambulatov
1
,
S A Nikolaevskii
1
,
I A Lutsenko
1
,
M. A. Kiskin
1
,
M. A. Shmelev
1
,
O B Bekker
2
,
N. N. Efimov
2
,
E. A. Ugolkova
1
,
V V Minin
1
,
A. A. Sidorov
1
,
I. L. Eremenko
1, 3
Publication type: Journal Article
Publication date: 2020-11-17
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The reaction of copper(II) trimethylacetate, [Cu(Piv)2]n (Piv = C(Me)3COO–), with caffeine (L) (Cu : L = 1 : 1) in anhydrous acetonitrile yielded the binuclear complex [Cu2(Piv)4(L)2] ⋅ 2CH3CN (I). The structure of the complex in the crystal was established by X-ray diffraction (CIF file CCDC no. 2 006 753), and the electronic structure was studied by ESR. The effect of caffeine coordination to the biogenic complexing agent was established: the in vitro biological activity of the obtained complex towards the non-pathogenic strain Mycolicibacterium smegmatis was eight times higher than that of free caffeine.
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Total citations:
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Citations from 2024:
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Yambulatov D. S. et al. Copper(II) Trimethylacetate Complex with Caffeine: Synthesis, Structure, and Biological Activity // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2020. Vol. 46. No. 11. pp. 772-778.
GOST all authors (up to 50)
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Yambulatov D. S., Nikolaevskii S. A., Lutsenko I. A., Kiskin M. A., Shmelev M. A., Bekker O. B., Efimov N. N., Ugolkova E. A., Minin V. V., Sidorov A. A., Eremenko I. L. Copper(II) Trimethylacetate Complex with Caffeine: Synthesis, Structure, and Biological Activity // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2020. Vol. 46. No. 11. pp. 772-778.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S1070328420110093
UR - https://doi.org/10.1134/S1070328420110093
TI - Copper(II) Trimethylacetate Complex with Caffeine: Synthesis, Structure, and Biological Activity
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Yambulatov, D S
AU - Nikolaevskii, S A
AU - Lutsenko, I A
AU - Kiskin, M. A.
AU - Shmelev, M. A.
AU - Bekker, O B
AU - Efimov, N. N.
AU - Ugolkova, E. A.
AU - Minin, V V
AU - Sidorov, A. A.
AU - Eremenko, I. L.
PY - 2020
DA - 2020/11/17
PB - Pleiades Publishing
SP - 772-778
IS - 11
VL - 46
SN - 1070-3284
SN - 1608-3318
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2020_Yambulatov,
author = {D S Yambulatov and S A Nikolaevskii and I A Lutsenko and M. A. Kiskin and M. A. Shmelev and O B Bekker and N. N. Efimov and E. A. Ugolkova and V V Minin and A. A. Sidorov and I. L. Eremenko},
title = {Copper(II) Trimethylacetate Complex with Caffeine: Synthesis, Structure, and Biological Activity},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2020},
volume = {46},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134/S1070328420110093},
number = {11},
pages = {772--778},
doi = {10.1134/S1070328420110093}
}
Cite this
MLA
Copy
Yambulatov, D. S., et al. “Copper(II) Trimethylacetate Complex with Caffeine: Synthesis, Structure, and Biological Activity.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 46, no. 11, Nov. 2020, pp. 772-778. https://doi.org/10.1134/S1070328420110093.