Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, volume 47, issue 8, pages 551-559
Coordination of Hexahydro-1,3,5-trimethyl-1,3,5-triazine in Cadmium(II) and Cobalt(II) Carboxylate Complexes
Shmelev M. A.
1
,
Voronina Yu K
1
,
Chekurova S S
2
,
Gogoleva N. V.
1
,
Ivanova T M
1
,
Lyamina O I
1
,
Fatyushina E V
1
,
Kiskin M. A.
1
,
Sidorov A. A.
1
,
Eremenko I. L.
1, 3
Publication type: Journal Article
Publication date: 2021-08-15
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 1.9
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The effect of bulky tridentate ligands on the geometry of carboxylate complexes was studied in relation to hexahydro-1,3,5-trimethyl-1,3,5-triazine (TACH). The reaction of [Co2Gd(NO3)(Piv)6(MeCN)2] (Piv is the pivalic acid anion) with TACH gave the complex [Co2Gd(NO3)(Piv)6(TACH)2] (I), in which the initial heterometallic moiety was retained and cobalt(II) ions coordinated the N-donor ligand to give a half-sandwich structure. The use of Cd(II) and Eu(III) pentafluorobenzoates in the reaction with TACH resulted in the isolation of only the homometallic complex [Cd(Pfb)2(TACH)2] (II) (Pfb is pentafluorobenzoic acid anion). Owing to high coordination number of cadmium(II) ion in II, a sandwich complex with two TACH molecules coordinated to the same metal ion was obtained. The structure of new complexes was determined by X-ray diffraction (CIF file CCDC nos. 2062230 (I) and 2062229 (II)). It was shown that binding of an N-donor ligand to a metal ion induces a significant distortion of the metal coordination polyhedra and a conformational change of hexahydro-1,3,5-trimethyl-1,3,5-triazine.
Citations by journals
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2
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
2 publications, 50%
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Mendeleev Communications
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Mendeleev Communications
1 publication, 25%
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Journal of Structural Chemistry
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Journal of Structural Chemistry
1 publication, 25%
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1
2
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Citations by publishers
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1
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3
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Pleiades Publishing
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Pleiades Publishing
3 publications, 75%
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Elsevier
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Elsevier
1 publication, 25%
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1
2
3
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Shmelev M. A. et al. Coordination of Hexahydro-1,3,5-trimethyl-1,3,5-triazine in Cadmium(II) and Cobalt(II) Carboxylate Complexes // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 8. pp. 551-559.
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Shmelev M. A., Voronina Yu. K., Chekurova S. S., Gogoleva N. V., Ivanova T. M., Lyamina O. I., Fatyushina E. V., Kiskin M. A., Sidorov A. A., Eremenko I. L. Coordination of Hexahydro-1,3,5-trimethyl-1,3,5-triazine in Cadmium(II) and Cobalt(II) Carboxylate Complexes // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 8. pp. 551-559.
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TY - JOUR
DO - 10.1134/S1070328421080078
UR - https://doi.org/10.1134%2FS1070328421080078
TI - Coordination of Hexahydro-1,3,5-trimethyl-1,3,5-triazine in Cadmium(II) and Cobalt(II) Carboxylate Complexes
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Shmelev, M. A.
AU - Voronina, Yu K
AU - Chekurova, S S
AU - Gogoleva, N. V.
AU - Ivanova, T M
AU - Lyamina, O I
AU - Fatyushina, E V
AU - Kiskin, M. A.
AU - Sidorov, A. A.
AU - Eremenko, I. L.
PY - 2021
DA - 2021/08/15 00:00:00
PB - Pleiades Publishing
SP - 551-559
IS - 8
VL - 47
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2021_Shmelev,
author = {M. A. Shmelev and Yu K Voronina and S S Chekurova and N. V. Gogoleva and T M Ivanova and O I Lyamina and E V Fatyushina and M. A. Kiskin and A. A. Sidorov and I. L. Eremenko},
title = {Coordination of Hexahydro-1,3,5-trimethyl-1,3,5-triazine in Cadmium(II) and Cobalt(II) Carboxylate Complexes},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2021},
volume = {47},
publisher = {Pleiades Publishing},
month = {aug},
url = {https://doi.org/10.1134%2FS1070328421080078},
number = {8},
pages = {551--559},
doi = {10.1134/S1070328421080078}
}
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MLA
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Shmelev, M. A., et al. “Coordination of Hexahydro-1,3,5-trimethyl-1,3,5-triazine in Cadmium(II) and Cobalt(II) Carboxylate Complexes.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 47, no. 8, Aug. 2021, pp. 551-559. https://doi.org/10.1134%2FS1070328421080078.