Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, volume 47, issue 10, pages 702-706
Electronic Structures of the Palladium(II) Complexes with Redox-Active o-Phenylenediimines
Ivanova T M
1
,
Kiskin M. A.
1
,
Sidorov A. A.
1
,
Maslakov K I
2
,
Savilov S. V.
1, 2
,
Eremenko I. L.
1, 3
Publication type: Journal Article
Publication date: 2021-10-01
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 1.9
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The electronic structures and the character of the electron density redistribution in the palladium complexes with the redox-active ligands in the oxidized and nonoxidized forms are studied by X-ray photoelectron spectroscopy. According to the photoelectron spectroscopic data, the redox-active ligands exist in different oxidation states due to the redox process proceeding “at ligand.” It is shown that the transition from the neutral to oxidized semiquinone form (from [Pd(LMe)2]·2Cl·H2O to [Pd\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$\left( {{\text{L}}_{{{\text{Ph}}}}^{{{\text{ISQ}}}}} \right)$$\end{document}2]) occurs in the ligand and involves no palladium ions, and the oxidation state of palladium remains unchanged: Pd(II). A significant difference in the photoelectron spectroscopic characteristics obtained for the oxidized trans-complex at 298 and 153 K indicates a specific electronic lability of this complex.
Citations by journals
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Russian Journal of Inorganic Chemistry
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Russian Journal of Inorganic Chemistry
1 publication, 100%
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1
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Citations by publishers
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Pleiades Publishing
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Pleiades Publishing
1 publication, 100%
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Ivanova T. M. et al. Electronic Structures of the Palladium(II) Complexes with Redox-Active o-Phenylenediimines // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 10. pp. 702-706.
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Ivanova T. M., Kiskin M. A., Sidorov A. A., Maslakov K. I., Savilov S., Eremenko I. L. Electronic Structures of the Palladium(II) Complexes with Redox-Active o-Phenylenediimines // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021. Vol. 47. No. 10. pp. 702-706.
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TY - JOUR
DO - 10.1134/S1070328421100031
UR - https://doi.org/10.1134%2FS1070328421100031
TI - Electronic Structures of the Palladium(II) Complexes with Redox-Active o-Phenylenediimines
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Ivanova, T M
AU - Kiskin, M. A.
AU - Sidorov, A. A.
AU - Maslakov, K I
AU - Eremenko, I. L.
AU - Savilov, S. V.
PY - 2021
DA - 2021/10/01 00:00:00
PB - Pleiades Publishing
SP - 702-706
IS - 10
VL - 47
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2021_Ivanova,
author = {T M Ivanova and M. A. Kiskin and A. A. Sidorov and K I Maslakov and I. L. Eremenko and S. V. Savilov},
title = {Electronic Structures of the Palladium(II) Complexes with Redox-Active o-Phenylenediimines},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2021},
volume = {47},
publisher = {Pleiades Publishing},
month = {oct},
url = {https://doi.org/10.1134%2FS1070328421100031},
number = {10},
pages = {702--706},
doi = {10.1134/S1070328421100031}
}
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Ivanova, T. M., et al. “Electronic Structures of the Palladium(II) Complexes with Redox-Active o-Phenylenediimines.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 47, no. 10, Oct. 2021, pp. 702-706. https://doi.org/10.1134%2FS1070328421100031.