,
volume 48
,
issue 2
,
pages 84-88
Thermodynamic Characteristics of Silver Perfluorobenzoates C6 F5 COOAg·0.5C6 F5 COOH and C6 F5 COOAg
I. P. MALKEROVA
1
,
D.B. Kayumova
1
,
E. V. Belova
1
,
M. A. Shmelev
1
,
A. A. Sidorov
1
,
I. L. Eremenko
1, 2
,
A. S. ALIKHANYAN
1
Publication type: Journal Article
Publication date: 2022-02-01
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
Abstract The thermodynamic characteristics of silver perfluorobenzoates C 6 F 5 COOAg·0.5C 6 F 5 COOH and C 6 F 5 COOAg were studied by thermogravimetry, differential scanning calorimetry, and mass spectrometry. It was found that vaporization of these compounds occurs incongruently to give metallic silver and C 6 F 5 COOH, C 12 F 10 , CO 2 , and C 18 F 14 molecules. Using the 2nd and 3rd laws of thermodynamics, the standard enthalpy of formation of silver perfluorobenzoate was found to be $${{\Delta }_{{\text{f}}}}H_{{{\text{298}}}}^{^\circ }$$ (C 6 F 5 COOAg, cr) = –1195.6 ± 15.7 kJ/mol and the standard enthalpy of formation of the pentafluorobenzoic acid radical was estimated to be $${{\Delta }_{{\text{f}}}}H_{{{\text{298}}.{\text{15}}}}^{^\circ }$$ (C 6 F 5 COO • , cr) = –878.6 ± 25.0 kJ/mol.
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MALKEROVA I. P. et al. Thermodynamic Characteristics of Silver Perfluorobenzoates C6F5COOAg·0.5C6F5COOH and C6F5COOAg // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2022. Vol. 48. No. 2. pp. 84-88.
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MALKEROVA I. P., Kayumova D., Belova E. V., Shmelev M. A., Sidorov A. A., Eremenko I. L., ALIKHANYAN A. S. Thermodynamic Characteristics of Silver Perfluorobenzoates C6F5COOAg·0.5C6F5COOH and C6F5COOAg // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2022. Vol. 48. No. 2. pp. 84-88.
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RIS
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TY - JOUR
DO - 10.1134/S107032842202004X
UR - https://doi.org/10.1134/S107032842202004X
TI - Thermodynamic Characteristics of Silver Perfluorobenzoates C6F5COOAg·0.5C6F5COOH and C6F5COOAg
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - MALKEROVA, I. P.
AU - Kayumova, D.B.
AU - Belova, E. V.
AU - Shmelev, M. A.
AU - Sidorov, A. A.
AU - Eremenko, I. L.
AU - ALIKHANYAN, A. S.
PY - 2022
DA - 2022/02/01
PB - Pleiades Publishing
SP - 84-88
IS - 2
VL - 48
SN - 1070-3284
SN - 1608-3318
ER -
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BibTex (up to 50 authors)
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@article{2022_MALKEROVA,
author = {I. P. MALKEROVA and D.B. Kayumova and E. V. Belova and M. A. Shmelev and A. A. Sidorov and I. L. Eremenko and A. S. ALIKHANYAN},
title = {Thermodynamic Characteristics of Silver Perfluorobenzoates C6F5COOAg·0.5C6F5COOH and C6F5COOAg},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2022},
volume = {48},
publisher = {Pleiades Publishing},
month = {feb},
url = {https://doi.org/10.1134/S107032842202004X},
number = {2},
pages = {84--88},
doi = {10.1134/S107032842202004X}
}
Cite this
MLA
Copy
MALKEROVA, I. P., et al. “Thermodynamic Characteristics of Silver Perfluorobenzoates C6F5COOAg·0.5C6F5COOH and C6F5COOAg.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 48, no. 2, Feb. 2022, pp. 84-88. https://doi.org/10.1134/S107032842202004X.